Lesson 8/9 - Lipids - Triglycerides/phospholipids Flashcards

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1
Q

Lipids all share these characteristics:

A

● All contain the elements Carbon, Hydrogen and Oxygen
● They are non-polar molecules due to the large number of C’s & H’s
and so are insoluble in water
● They are soluble in other organic solvents (eg. alcohols)

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2
Q

What are the 2 main groups of lipids?

A

● Triglycerides (the fats and oils) - a
component of our diet
● Phospholipids - a component of cell
membranes

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3
Q

How are triglycerides formed?

A

By the condensation of 1 molecule of glycerol and 3 molecules of fatty acid.

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4
Q

Which bond is created when glycerol bonds to a fatty acid (RCOOH) ?

A

Ester bond

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5
Q

Which group of a fatty acid can be saturated or unsaturated?

A

R group

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6
Q

What’s the difference between a triglyceride and a phospholipid?

A

In a phospholipid, 1 of the fatty acid’s of a triglyceride is substituted with a phosphate containing group.

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7
Q

What’s a fatty acid?

A

● Long hydrocarbon chain with a carboxylic acid group at one
end
● Some fatty acids contain carbon double bonds and some don’t

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8
Q

What’s the emulsion test for lipids?

A
  1. Mix the sample being tested with alcohol (eg. ethanol) in a test tube
  2. Shake the tube thoroughly
  3. Add cold water and shake gently
  4. If a milky-white emulsion is formed, this indicates the presence of a lipid
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9
Q

Whats the Difference between saturated and unsaturated fatty acids?

A

● Saturated fatty acids have only C-C so form linear hydrocarbon chains.
● Unsaturated fatty acids have one or more C=C which causes the hydrocarbon chain to bend.

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10
Q

Saturated definition

A

No double bonds between carbon atoms.

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11
Q

Mono-unsaturated definition

A

Contains 1 double bond between carbon atoms.

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12
Q

Polyunsaturated definition

A

More than 1 double bond between carbon atoms.

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13
Q

Patterns/formation of saturated and unsaturated fatty acids

A

● Saturated fatty acids fit closely together in a regular pattern.
● Unsaturated fatty acids push each other apart forming irregular patterns.

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14
Q

Properties of saturated fatty acids

A

● Contain only C-C bonds (and
therefore form linear hydrocarbon
chains)
● Fatty acids can pack closely together
● Strong attractions (intermolecular
bonds) between fatty acid chains
● High melting points
● Solids at room temperature

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15
Q

Properties of unsaturated fatty acids

A

● Contain one or more C=C (causing the
hydrocarbon chains to bend)
● The nonlinear chains do not allow the
fatty acid molecules to pack closely
together
● Weaker attractions (intermolecular bonds)
between fatty acid chains
● Lower melting points
● Liquids at room temperature

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16
Q

Why are fats generally solid at room temperature?

A

Fats are generally made of saturated fatty acids hence why they are solid at room temperature.

17
Q

Why are oils generally liquid at room temperature?

A

Oils are generally made of unsaturated fatty acids hence why they are liquid at room temperature.

18
Q

Which term describes triglycerides being large, insoluble molecules?

A

Hydrophobic

19
Q

What happens during condensation? (triglyceride)

A

● Produces a triglyceride
● Formed from a glycerol
and 3 fatty acids
● 3 water molecules are
released
● 3 ester bonds formed

20
Q

What happens during hydrolysis? (triglyceride)

A

● Triglyceride is split by the
addition of 3 water
molecules
● 3 ester bonds broken
● Glycerol and 3 fatty acids
is formed

21
Q

Which intermolecular bonds in saturated and unsaturated fatty acids are stronger?

A

The intermolecular bonds between the saturated fatty acids are stronger than the ones between the unsaturated bonds, as they closer together.

22
Q

Which part of a phospholipid is hydrophobic (repels water) and which is hydrophilic (attracts water) ?

A

hydrophobic (repels water) - fatty acid
hydrophilic (attracts water) - phosphate molecule

23
Q

Which fatty acids does a phospholipid contain?

A

A saturated and an unsaturated fatty acid

24
Q

How do phospholipids position themselves when placed in water?

A

So that the heads are as close to water as possible and the tails are as far from water as possible.

25
Q

What are some other roles of lipids?

A

● Lipids are a source of energy - provide more than double the
energy as the same amount of carbohydrate.
● Waterproofing (as they are hydrophobic) - waxy, lipid cuticles are
found in both plants and insects to conserve water (reduce water
loss)
● Insulation - fats are slow conductors of heat, so, a layer of fat
stored under the skin helps to retain body heat (prevent it being
lost)
● Protection - fat is often stored round delicate organs eg. the
kidney, to protect from damage
● Buoyancy - slightly less dense than water
● Electrical insulator - surrounds nerves to increase the speed of
electrical impulses