Flammable Liquids Flashcards
Where are Additives found?
Bulk petroleum storage facilities, stored in smaller tanks
pg.2
“Products found at bulk petroleum storage facilities that are stored in smaller tanks and are added to gasoline or diesel fuel in very small quantities. Additives are typically similar to diesel fuel in combustibility, but may present greater health hazards.”
Additives:
products that are added to gasoline or diesel fuel in small amounts
pg.2
“Products found at bulk petroleum storage facilities that are stored in smaller tanks and are added to gasoline or diesel fuel in very small quantities. Additives are typically similar to diesel fuel in combustibility, but may present greater health hazards.”
Aqueous Film Forming Foam (AFFF) and Alcohol Resistant Aqueous Film Forming Foam (AR-AFFF):
most commonly used foams.
Synthetic foam w/ alcohol resistant properties
AFFF ranges from 1 to 6 percent.
pg.2
“Aqueous Film Forming Foam (AFFF) and Alcohol Resistant Aqueous Film Forming Foam (AR-AFFF): AFFF and AR-AFFF are the most commonly used foams available today, with the AR version making it the most versatile foam as well. AFFF is synthetic foam with the basic elements being fluorochemical surfactants, hydrocarbon surfactants, and solvents. Just as in AR- FFFP, the addition of a polymer gives AR-AFFF its alcohol resistant properties. These versatile foams have excellent knockdown ability, good heat resistance, good fuel tolerance, good vapor suppression and in the AR version, excellent alcohol tolerance. AFFF is available in a wide range of percentages from 1% to 6%.”
An ARFF unit has a minimum of how many gallons of foam concentrate?
100 gallons
pg.2
“ARFF Unit: This is a self-contained unit specifically designed to have a pump-and-roll capability and a minimum of 100 gallons of foam concentrate; may have duel agent application ability and duel agent application. The minimum ARFF vehicle requirements are established by Title 14 Code of Federal Regulations Part 139 – Certification of Airports, NFPA 414: Standard for Aircraft Rescue and Fire-fighting Vehicles, and NFPA 1901: Standard for Automotive Fire Apparatus.”
an AR Foam unit is designed to respond to what type of incidents?
flammable liquids
pg.2
“AR Foam Unit: A self-contained fire engine that has been specifically designed to respond to flammable liquids incidents within the NOVA region. Units carry AR-AFFF foam and may have pump-and-roll capability.”
What is an Auto-Ignition Temperature?
lowest temp where a substance ignites without other ignition source
pg.2
“The lowest temperature where a substance will auto-ignite and combust without any other sources of ignition.”
Petroleum products handled by pipelines and in bulk storage are measured by what?
Barrels
pg.2
“Barrel: Petroleum products handled by pipelines and in bulk storage are measured in barrels. A barrel (abbreviated bbl) contains 42 U.S. gallons.”
A Barrel contains how many gallons?
42
pg.2
“Barrel: Petroleum products handled by pipelines and in bulk storage are measured in barrels. A barrel (abbreviated bbl) contains 42 U.S. gallons.”
Combustible liquids have a flash point above ______ degrees Fahrenheit?
100
pg.2
“Combustible Liquid: Liquid having a flash point above 100 degrees Fahrenheit (37.78 Celsius) and below 200 degrees Fahrenheit (93.33 Celsius)”
Combustible Liquids have a flash point below _____ degrees Fahrenheit?
200
pg.2
“Combustible Liquid: Liquid having a flash point above 100 degrees Fahrenheit (37.78 Celsius) and below 200 degrees Fahrenheit (93.33 Celsius)”
Fixed Facility Containment:
Primary containment:
Includes tanks and piping
product is contained under normal circumstances
pg.2
“Primary containment: Includes tanks and piping where product is contained under normal circumstances.”
Fixed Facility Containment:
Secondary containment:
Diked area around tanks where product will be contained in the initial stages of an incident.
includes controlled drainage areas at loading racks and other areas where spills are likely
pg.2
“Secondary containment: Diked area around tanks where product will be contained in the initial stages of an incident. Secondary containment also includes controlled drainage areas at loading racks and other areas where spills are likely to occur. Product may be diverted to secondary containment from other areas, or may be diverted from secondary containment to remote impounding areas.”
Fixed Facility Containment:
Tertiary containment:
pg.3
“Tertiary containment: Additional area where product can be contained in the event of a catastrophic incident. Product may also be diverted to this area for remote impounding.”
Portable Protection:
pg.3
“Portable Protection: Foam delivery system that can be carried or wheeled.”
Semi-Fixed Foam System:
similar to a dry standpipe
piping and foam discharge outlets to protect hazard areas but have no supply of foam or water
requires action by FD
pg.3
“Semi-Fixed Foam System: A foam delivery system that is similar in concept to a dry standpipe. This system consists of piping and foam discharge outlets that are installed to protect hazard areas but have no supply of foam or water connected to them. These systems require action by the fire department.”
Topside Foam System:
foam solution is combined with air to produce finished foam.
piping designed to deliver finished foam from above the surface of the contents of the tank.
pg.3
“Topside Foam System: A system of fixed foam chambers (a device where foam solution is combined with air to produce finished foam) and piping designed to deliver finished foam from above the surface of the contents of the tank. This may be a fixed or semi- fixed system.”
Subsurface Foam System:
foam solution is injected at the bottom of the tank and rises to the surface of the product.
pg.3
“A system in which foam solution is injected at the bottom of the tank and rises to the surface of the product. This may be a fixed or semi-fixed system.”
Rim Protection:
pg.3
“Rim Protection: A system used on some floating roof tanks where protection is provided to the rim of the roof only by use of a foam dam.”
Flammable liquids have a flash point below how many degrees?
100
pg.3
“Flammable Liquid: Any liquid having a flash point below 100 degrees Fahrenheit (37.78 degrees Celsius) and having a vapor pressure not exceeding 40 psi absolute.”
The vapor pressure on a flammable liquid does not exceed what?
40 psi absolute
pg.3
“Flammable Liquid: Any liquid having a flash point below 100 degrees Fahrenheit (37.78 degrees Celsius) and having a vapor pressure not exceeding 40 psi absolute.”
Flexible Fuel Vehicle (FFV):
pg.3
“An alternative fuel vehicle with an internal combustion engine designed to run on more than one fuel, usually gasoline blended with either ethanol or methanol fuel.”
Fluoro-Protein Foam (FPF) is available in what versions?
3% and 6%
pg.3
“Fluoro-Protein Foam (FPF): Fluoroprotein foam is much like protein foam, but with a fluorocarbon surfactant added to the ingredients. This foam provides good knockdown ability, excellent heat resistance, excellent fuel tolerance, excellent vapor suppression, and no alcohol tolerance. FPF is available in 3% and 6% versions.”
Foam Application Methods (Fixed Facility):
Type II:
pg.3
“Fixed foam outlet, either subsurface or topside, designed to deliver finished foam to surface of burning liquid with restricted agitation.”
Foam Application Methods (Fixed Facility):
Type I:
pg.3
“Obsolete method no longer used in the NOVA region. This type of application was intended to deliver finished foam to burning surface gently and with minimal agitation”
Foam Application Methods (Fixed Facility):
Type III:
pg.4
“Type III: Use of master streams and hand line nozzles to deliver finished foam to the burning surface in a manner resulting in some agitation of the surface.”
What type of foam appliction is obsolete?
Type I
pg.3
“Type I: Obsolete method no longer used in the NOVA region. This type of application was intended to deliver finished foam to burning surface gently and with minimal agitation.”
What type of foam application uses master streams and hand line nozzles to deliver finished foam to the burning surface, resulting in some agitation to the surface?
Type III
pg.4
“Type III: Use of master streams and hand line nozzles to deliver finished foam to the burning surface in a manner resulting in some agitation of the surface.”
Foam Task Force compliment:
2 AR foam units
2 engines
1 pump and roll unit
1 BC
1 hazardous materials assest
pg.4
“Foam Task Force: Response consisting of two AR foam units, one pump-and-roll unit, two engines, one battalion chief, and one hazardous materials asset (if not already dispatched).”
Where is Hydrocarbon found?
What are typical Hyrdocarbon fuels?
in petroleum products
gasoline and diesel fuels
pg.4
“Hydrocarbon: Organic compound found in petroleum products, containing primarily hydrogen and carbon. Most hydrocarbons are refined from crude oil or have been extracted from vegetable fiber. Typical hydrocarbon fuels include gasoline and diesel fuel.”
Hydrophilic:
pg.4
“A substance having a strong affinity for water.”
Loading Rack (Fixed Facility):
pg.4
“Area where tank vehicles are loaded with product for delivery outside the facility.”
Non-Intervention Mode:
pg.4
“Taking no immediate action other than isolating the area until the risk of intervention is reduced to an acceptable level, as operations may transition between offensive and defensive strategies. This operating mode may be used while assembling resources to commence an offensive attack.”
Petroleum Distillate:
pg.4
“Petroleum Distillate: Combustible liquids, including diesel fuel, heating oil, and jet fuel.”
Northern VA is served by what 2 petroleum pipeline companies?
Colonial Pipeline and Plantation Pipeline.
pg.4
“Pipeline: DOT-regulated carrier of product. The Northern Virginia region is served by two petroleum pipeline companies, Colonial Pipeline and Plantation Pipeline. These pipelines are underground for most of their route.”
Pipeline Manifold (Fixed Facility):
pg.4
“Pipeline Manifold (Fixed Facility): Piping that incorporates control valves to deliver product from the pipeline to storage tanks.”
Polar Solvent:
pg.5
“Polar Solvent: Flammable liquids that mix readily with water. Examples include alcohols, ketones, and lacquers.”
Product:
pg.5
“Generic term for petroleum fuels.”
Product Pumps (Fixed Facility):
pg.5
“Pumps, usually located within secondary containment, which deliver product.”
Where are Pump-and-roll units usually found?
airports
pg.5
“Pump-and-roll Unit: A self-contained unit that is specifically designed to respond to flammable liquid incidents with in the NOVA region. Units may carry AFFF or AR-AFFF foam. These units are typically found at airports.”
Pump-and-roll Units are designed to respond to what type of incidents with in the NOVA region.
flammable liquid incidents
pg.5
“Pump-and-roll Unit: A self-contained unit that is specifically designed to respond to flammable liquid incidents with in the NOVA region. Units may carry AFFF or AR-AFFF foam. These units are typically found at airports.”
Reformulated Gasoline (RFG):
Gasoline in which the composition has been changed to reduce automotive emissions.
pg.5
“Reformulated Gasoline (RFG): Gasoline in which the composition has been changed to reduce automotive emissions. RFG has lower levels of volatile compounds and benzene and contains oxygenates such as ether or ethanol. RFG with greater than 10% oxygenate additives reacts more like a polar solvent and should be treated as such.”
Passenger vehicles with leaking tanks are considered to be what type of a spill?
Small spill
pg.5
“Small Spill: A spill occurring from a container or package approximately 55 gallons or less, a small cylinder, or a small leak from a large container with a minimum flow. Passenger vehicles with leaking tanks are considered small spill responses.”
A small spill is how many gallons or less?
55
pg.5
“Small Spill: A spill occurring from a container or package approximately 55 gallons or less, a small cylinder, or a small leak from a large container with a minimum flow. Passenger vehicles with leaking tanks are considered small spill responses.”
A large spill is how many gallons or more?
exceeding 55 gallons or multiple spills from multiple small packages or containers.
pg.5
“Large Spill: A large spill exceeding 55 gallons or multiple spills from multiple small packages or containers. Large spill responses include any incident at or involving pipelines, horizontal tanks, tank farms, or flammable liquid tanker trucks or rail cars.”
Tank Construction Features (Fixed Facility):
Cathodic Protection:
A system of corrosion protection that uses a small electrical
current.
pg.5
Tank Construction Features (Fixed Facility):
Cone Roof:
Cone Roof: A large tank with a fixed steel roof and an exposed product surface within the tank.
pg.5
Tank Construction Features (Fixed Facility):
Covered Floating Roof:
pg.5
“Covered Floating Roof: A large tank that has an external steel roof and an internal floating roof.”
Tank Construction Features (Fixed Facility):
Double Bottom:
pg.5
Double Bottom: A feature of large tanks designed to prevent environmental contamination from a leak at the bottom of the tank. Leak detection equipment is typically provided within the space between the double tank bottoms.
Tank Construction Features (Fixed Facility):
Foam Dam:
pg.5
“Foam Dam: Fire protection feature installed on some floating roofs to limit foam application to the rim area of the roof.”
Tank Construction Features (Fixed Facility):
Eye Brow Vent:
hooded metal structure on the top edge of a fixed roof tank
provides weather protection over vent ports for floating roof tank
pg.6
“Eye Brow Vent: A hooded metal structure attached to the exterior top edge of a fixed roof tank, which provides weather protection over the vent ports for an internal floating roof tank.”
Tank Construction Features (Fixed Facility):
Geodesic Dome Roof:
pg.6
“Geodesic Dome Roof: A lightweight roof type of characteristic design.”
Tank Construction Features (Fixed Facility):
Horizontal Tank:
pg.6
“Horizontal Tank: An aboveground tank of smaller capacity, typically not more than 30,000 gallons, oriented with the cylinder in a horizontal position. These tanks may be of single or double wall construction. Tanks with single wall construction should be provided with secondary containment.”
Tank Construction Features (Fixed Facility):
Open Floating Roof:
pg.6
“Open Floating Roof: A large tank that is open at the top but has a roof that floats on top of the product within the tank.”
Tank Construction Features (Fixed Facility):
Weak Roof to Shell Seam:
pg.6
“Weak Roof to Shell Seam: A weld that is less strong allowing the roof to blow away in an explosion, exposing the surface of the interior of the tank.”
Vapor Density:
The weight of a vapor compared to the weight of dry air.
pg.6
“The weight of a vapor compared to the weight of dry air. Substances lighter than air are said to have vapor densities less than 1.0 and those heavier than air have a vapor density greater than 1.0.”
Substances lighter than air have a vapor densiy of what?
less than 1.0
pg.6
“Substances lighter than air are said to have vapor densities less than 1.0 and those heavier than air have a vapor density greater than 1.0.””