Electrochemistry and other Physicochemical and Instrumental method Flashcards

1
Q

Study of chemical processes that cause electrons to move.

A

Electrochemistry

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2
Q

Movement of electrons, generated by movements of electrons from one element to another reaction (Redox Reaction)

A

Electricity

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3
Q

Transfer of charge, measured in Amperes

A

Electric current

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4
Q

Surfaces at which oxidation and reduction half-reactions occur

A

Electrodes

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5
Q

Involves electron loss and electron gain

A

Half-reaction in Redox reaction

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6
Q

Potential of a cell consisting of electrode concerned acting as a cathode and the standard hydrogen electrode as an anode.

A

Electrode Potential

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7
Q

Study of voltage, current, time relationships during electrolysis carried out in a cell.

A

Voltammetry

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8
Q

Electrodes used in Voltammetry

A

Working/Indicator Electrode
Reference Electrode
Auxilliary Electrode

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9
Q

Potential is dependent on concentration of the ion to be determined

A

Working/Indicator Electrode

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10
Q

Maintains a constant potentials throughout the measurement

A

Reference Electrode

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11
Q

Used to measure the potential of the working electrode

A

Reference Electrode

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12
Q

Where electrolysis takes place

A

Working/Indicator Electrode

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13
Q

Carries the electrolysis current and works with the working electrode

A

Auxilliary Electrode

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14
Q

Method of analysis based on current measurement resulting from electrolysis of an electronegative species at a given electrode potential under controlled condition.

A

Polarography ⭐

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15
Q

Dropping Mercury electrode

A

Working Electrode

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16
Q

Pool of Mercury at the base of the cell

A

Auxilliary Electrode

17
Q

Study of electrode potentials and determine the CONCENTRATION of an ionic species in a solution

A

Potentiometry

18
Q

Determination of pH / conc of H+ ions

A

Potentiometry

19
Q

Electrodes used in Potentiometry

A

Hydrogen Electrode
Quinhydrone Electrode
Glass Electrode

20
Q

Ultimate standard for pH measurements

A

Hydrogen Electrode

21
Q

Avoid difficulties with the hydrogen electrode

A

Quinhydrone Electrode

22
Q

Most popular and replaces both electrode

A

Glass Electrode

23
Q

Rotatory Power

A

Optical Activity

24
Q

Ability or power to rotate the plane of polarized light

A

Rotatory Power/Optical Activity

25
Q

Devices used in determination of optical activity

A

Polariscope
Polarising microscope

26
Q

Used for the examination of liquid

A

Polariscope

27
Q

Used for the examination of solids

A

Polarizing microscope

28
Q

Prism made of iceland spar/Calcite

A

NICOL Prism

29
Q

Measurement of the light which is bent

A

Refractometry

30
Q

The extent and direction of refraction are dependent upon the difference between the ___________ of the two substance

A

densities

31
Q

Ratio of the velocity of light in air to the velocity of light in the medium

A

Index of Refraction

32
Q

Index of refraction is the ratio of the sine of the angle of _______ to the since of the angle of ______

A

Index of refraction is the ratio of the sine of the angle of incidence to the since of the angle of refraction

33
Q

The angle between ray in the first medium and the normal

A

Angle of incidence

34
Q

Corresponding angle in the second medium

A

Angle of refraction

35
Q

Uses of Refractometry

A

Identity and purity of drugs

Strength and purity of solution or proportion in which liquids are mixed