Electrochemistry and other Physicochemical and Instrumental method Flashcards

1
Q

Study of chemical processes that cause electrons to move.

A

Electrochemistry

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2
Q

Movement of electrons, generated by movements of electrons from one element to another reaction (Redox Reaction)

A

Electricity

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3
Q

Transfer of charge, measured in Amperes

A

Electric current

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4
Q

Surfaces at which oxidation and reduction half-reactions occur

A

Electrodes

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5
Q

Involves electron loss and electron gain

A

Half-reaction in Redox reaction

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6
Q

Potential of a cell consisting of electrode concerned acting as a cathode and the standard hydrogen electrode as an anode.

A

Electrode Potential

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7
Q

Study of voltage, current, time relationships during electrolysis carried out in a cell.

A

Voltammetry

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8
Q

Electrodes used in Voltammetry

A

Working/Indicator Electrode
Reference Electrode
Auxilliary Electrode

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9
Q

Potential is dependent on concentration of the ion to be determined

A

Working/Indicator Electrode

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10
Q

Maintains a constant potentials throughout the measurement

A

Reference Electrode

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11
Q

Used to measure the potential of the working electrode

A

Reference Electrode

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12
Q

Where electrolysis takes place

A

Working/Indicator Electrode

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13
Q

Carries the electrolysis current and works with the working electrode

A

Auxilliary Electrode

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14
Q

Method of analysis based on current measurement resulting from electrolysis of an electronegative species at a given electrode potential under controlled condition.

A

Polarography ⭐

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15
Q

Dropping Mercury electrode

A

Working Electrode

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16
Q

Pool of Mercury at the base of the cell

A

Auxilliary Electrode

17
Q

Study of electrode potentials and determine the CONCENTRATION of an ionic species in a solution

A

Potentiometry

18
Q

Determination of pH / conc of H+ ions

A

Potentiometry

19
Q

Electrodes used in Potentiometry

A

Hydrogen Electrode
Quinhydrone Electrode
Glass Electrode

20
Q

Ultimate standard for pH measurements

A

Hydrogen Electrode

21
Q

Avoid difficulties with the hydrogen electrode

A

Quinhydrone Electrode

22
Q

Most popular and replaces both electrode

A

Glass Electrode

23
Q

Rotatory Power

A

Optical Activity

24
Q

Ability or power to rotate the plane of polarized light

A

Rotatory Power/Optical Activity

25
Devices used in determination of optical activity
Polariscope Polarising microscope
26
Used for the examination of liquid
Polariscope
27
Used for the examination of solids
Polarizing microscope
28
Prism made of iceland spar/Calcite
NICOL Prism
29
Measurement of the light which is bent
Refractometry
30
The extent and direction of refraction are dependent upon the difference between the ___________ of the two substance
densities
31
Ratio of the velocity of light in air to the velocity of light in the medium
Index of Refraction
32
Index of refraction is the ratio of the sine of the angle of _______ to the since of the angle of ______
Index of refraction is the ratio of the sine of the angle of incidence to the since of the angle of refraction
33
The angle between ray in the first medium and the normal
Angle of incidence
34
Corresponding angle in the second medium
Angle of refraction
35
Uses of Refractometry
Identity and purity of drugs Strength and purity of solution or proportion in which liquids are mixed