Chemistry Unit 2 Flashcards
What is the reaction for neutralisation?
Acid + base –> salt + water
What are the 2 main uses of precipitation reactions?
To remove poisonous ions from drinking water
Treating sewage
For the acid + metal reaction, what indicates the rate of reaction and what confirms the hydrogen?
Rate of reaction = rate at which bubbles of hydrogen are given off
Hydrogen confirmed by the burning splint test giving a squeaky pop
Describe how you would make insoluble salts
Use precipitation
Work out the positive and negative ion of the salt
Mix a nitrate of positive ion in solution with sodium and the negative ion in solution (this is because most nitrates and group 1 compounds are soluble)
You would then get a precipitate of the wanted salt (solid) and sodium nitrate solution in the flask
Then you filter the salt from the solution, wash it and dry it on filter paper
Describe how you make a soluble salt using an alkali
You can’t add an excess of alkali because you can’t tell whether the reaction has finished in this case
You add just the right amount of alkali to acid and order to neutralise the acid (you use an indicator to work out how much alkali is needed to neutralise the acid)
You repeat using exactly the same amounts of acid and alkali so that the salt isn’t contaminated by the indicator
Crystallise the salt
What is ammonium nitrate used for and why?
Very good fertiliser
It has nitrogen from 2 sources (ammonia and nitric acid) and plants need nitrogen to make proteins
Describe how you make a soluble salt using a metal or insoluble base
Pick the correct acid and metal / insoluble base to make the salt you need
Add the insoluble base or metal to the acid and the solid will dissolve in the acid as it reacts
When all acid has been neutralised, the excess solid won’t dissolve
Then filter out the excess solid to get the salt solution
To get pure, solid crystals of the salt, use crystallisation
What is an acid?
A substance with a pH below 7 that forms H+ ions in water
What is an alkali?
A base that dissolves in water (forms OH- ions in water)
Describe crystallisation
To get pure, solid crystals of the salt you use crystallisation
You evaporate some of the water to make the solution more concentrated and then leave the rest to evaporate very slowly
What are the 2 neutralisation reactions and the other similar reaction?
Acid + metal oxide –> salt + water
Acid + metal hydroxide –> salt + water
Similar reaction:
Acid + metal –> salt + hydrogen
What are the 2 ways of making soluble salts?
Using metal or insoluble base
Using an alkali
What salts do hydrochloric, sulphuric and nitric acids produce?
Hydrochloric –> chloride
Sulphuric –> sulphate
Nitric –> nitrate
What is a base?
A substance with a pH above 7
What happens when ammonia reacts with an acid?
Ammonia + hydrochloric acid –> ammonium chloride
Ammonia + sulphuric acid –> ammonium sulphate
Ammonia + nitric acid –> ammonium nitrate
What does diatomic mean?
An element that naturally has 2 covalently bonded atoms such as H^2
Describe electroplating
You can coat the surface of one metal with another metal
The negative electrode is the metal to be plated and the positive electrode is the metal that will plate it. The electrolyte also contains the ions if the playing metal
The ions that plate the metal come from the solution and the positive electrode keeps the solution topped up
Which substances made by electrolysis are diatomic?
Hydrogen at the cathode
Halides at the anode
Show how sodium chloride solution would break down in electrolysis
Hydrogen is less reactive so at the negative electrode, the H+ ions lose their charge
Because a halogen will form at the positive electrode if possible, the Cl- ions will lose their charge and become the halogen chlorine
When the electricity is turned off, the Na+ and OH- ions are left so they react to form sodium hydroxide
What are the 2 reasons for electroplating?
Decoration (plate a cheap metal with an expensive metal to make it look expensive)
Conduction (copper often plates metals for electronic circuits because it conducts electricity so well)
Why does the positive electrode have to be replaced?
When oxygen forms at the electrode, it reacts with the carbon of the electrode and forms carbon dioxide
This reaction eats away the carbon of the electrode
What are the 4 uses of electrolysis?
Extract a metal from an ore
Purify copper
Create substances from salt
Improve surface of a metal
What are the cathode and anode?
Anode is positive electrode
Cathode is negative electrode
What is brine?
Sodium chloride solution
How do you remember the difference between oxidation and reduction?
OIL RIG
Oxidation is loss (of electrons)
Reduction is gain (of electrons)
Why is electrolysis more complicated in aqueous solutions?
Because ions in the water are present as well as the ions in the compound
What is electrolysis?
The breakdown of a substance by passing electricity through it
Why isn’t an ionic solid an electrolyte?
The ions are not free to move so the current cannot pass through them
What are the rules about reactions at the positive electrode?
If hydroxide and halide ions are present, halogens will be produced and the hydroxide will stay as ions
If no halide is present, oxygen will be formed
Why is electrolysis of aluminium oxide so expensive and what is done to counter this?
It has to be heated up to 2000C for it to become molten
Cryolite (less common aluminium ore) is added and this brings the melting point down to 900C
What will form at the positive electrode if possible?
A halogen
What is an electrolyte?
An ionic substance that is either a liquid or dissolved in water
What are the rules about reactions at the negative electrode?
If metal ions and hydrogen ions are present, the metal ions will stay in solution and hydrogen will form if the metal is more reactive than hydrogen
This is because, the more reactive an element, the keener it is to stay as ions
What is a half equation?
A chemical equation that shows how an ion gains or loses electrons at an electrode
2H+ + 2e- –> H^2
2Cl- –> Cl^2 + 2e-
How do OH- ions oxidise? (Chemical equation)
4OH- –> O^2 + 2H^2O + 4e-
What 2 chemical properties are needed to use electrolysis in breaking down of a substance?
Substance is ionic
Ions are free to move
Why is electrolysis avoided if possible?
Expensive due to the cost of the electricity as a high current is needed
Why is electrolysis used for purifying copper?
Copper needs to be very pure for use as electrical wiring
What is Faraday’s law of electrolysis?
The higher the current used, the faster the substance is produced
What are the 2 reasons that the electrolysis of sodium chloride solution is useful in industry?
Chlorine is useful in bleach and plastics
Sodium hydroxide is a very strong alkali and used widely in the chemical industry
What is dynamic equilibrium?
When 2 conflicting sources make a reversible reaction not lose or gain any more products
What is an endothermic reaction?
A chemical reaction that absorbs heat from the surroundings
What is the industrial problem with reversible reactions?
If the reactants and products can’t escape the reaction area, the reaction would reach a state of equilibrium and the products would turn into the reactants just as much as the other way round
Is exothermic or endothermic rarer?
Endothermic reactions are rarer
What is a reversible reaction?
A reaction where the end products can react back into the original reactants
What is the main endothermic reaction?
When calcium carbonate thermally decomposes to form calcium oxide and carbon dioxide
Give 3 ways in which exothermic reactions are used
Heating
Generating electricity
Self-heating cans
What relates exothermic / endothermic and reversible reactions?
The forward reaction would be exothermic / endothermic and the backward reaction would be the opposite
Give 2 ways in which endothermic reactions are used
Ice packs for injuries
Self-cooling cans for drinks
What are the 3 main exothermic reactions?
Burning fuels
Neutralisation reactions
Oxidation reactions
How do we show a reaction is reversible in a chemical formula?
Double-headed arrow
What is an exothermic reaction?
A chemical reaction that transfers heat to the surroundings
Describe the experiment you use to see the effect of a catalyst on rate of reaction
You put hydrogen peroxide in a conical flask and put in a catalyst
Use the volume of gas given off (oxygen gas) to calculate the rate of reaction
Do this method for all the different catalysts to be tested
How do you measure rate of reaction using change in mass?
If a reaction produces a gas, you can measure the rate of reaction by looking at the change in mass (gas is lost)
You measure the change in mass by using a balance and looking at how fast the mass goes down
What are the 2 advantages of using catalysts in industrial reactions?
Increases rate of reaction so the plant doesn’t need to operate for as long saving money
Allows the reaction to work at lower temperatures and pressures
What is the biggest problem with catalysts?
They are very specific
Only one type of catalyst will catalyse a specific reaction
Describe the experiment you use to see the effect of temperature on rate of reaction
Let the 2 clear solutions of sodium thiosulphate and hydrochloric acid react in a comical flask and use the precipitation method to calculate the rate of reaction
Then use a water bath to heat the solutions up before mixing them and calculate the rate of reaction
The second reaction should be faster
How does surface area affect the rate of reaction?
If the surface area is larger, more of the reactant is exposed meaning the particles of the other reactant are more likely to collide with it
How do you measure the rate of reaction with the volume of gas given off?
You use a gas syringe to collect up the gas of the reaction
The more gas given off in a given time, the faster the reaction
Why is a catalytic converter needed?
The harmful gases of carbon monoxide and nitrogen oxides are changed to the much less harmful carbon dioxide and nitrogen
What are the 2 problems with the precipitation rate of reaction experiment?
Different people might not agree on the exact point that the mark disappears
Only works for reactions where the initial solution is clear
What is collision theory?
The theory that substances react when the particles of the reactants collide, break apart and then re-form to create new substances
Describe the experiment you use to see the effect of surface area on rate of reaction
You put marble chips and hydrochloric acid in conical flask and use the volume of gas given off method to calculate the rate of reaction
You then do the same but crunch up the chips more which gives a larger surface area
The second reaction should happen faster
How does concentration change the rate of reaction?
If the particles are more crowded (higher concentration) they are much more likely to collide so the reaction is faster
What are successful collisions?
Collisions that result in a chemical reaction
Describe the experiment you use to see the effect of concentration on rate of reaction
You use the change in mass method to calculate the rate of reaction of magnesium metal and dilute hydrochloric acid
You do the sane reaction with a higher concentration hydrochloric acid
The second reaction should have a higher rate
How do catalysts work?
The catalyst particles collide with the reactant particles and lower the activation energy by providing an alternative route for the reaction
What are the 4 factors that can change the speed of a reaction?
Temperature, concentration, surface area and pressure
Where are catalysts used?
They are used in industrial chemical reactions where there isn’t much time
They are used in catalytic converters