ChECal Flashcards
A unit operation in which a soluble component is removed from an inert solid by a solvent which preferentially dissolves the soluble matter is known as
Leaching
The unit operation by which soluble components of a liquid mixture are dissolved in a liquid immiscible with the insoluble component is
Solvent Extraction
Tea percolation employs
Leaching
Leaching of sugar from sugar beets is done using
Hot water
In a counter-current extractor, as the axial mixing increases, the extraction efficiency
Decreases
Bollman extractor is used for ____
extraction of oil from oilseed
Radioactive nuclear waste is treated in
Pulsed column extractor
Acetic acid will be most economically separated from a dilute solution of acetic acid in water by
Solvent extraction
Liquid-liquid extraction is based on the differences in ___
solubility
Heats sensitive materials with very high latent heat of vaporization may be economically separated using ___
liquid extraction
Which method is more efficient, a single large washing or repeated small washing?
repeated small washing
Which of the following equipment is not used in liquid-liquid extraction?
Pachuka tank
Heat sensitive materials with very high latent heat of vaporisation may be economically separated using
Liquid extraction
The solvent used in liquid extraction should not have high latent heat of vaporization, because
Its recovery cost by distillation may be prohibitatively high
Solvent extraction is the terminology applied to the liquid-liquid extraction, which is preferred for the separation of the components of liquids, when
extracting solvent is cheaply & abundantly available.
In a counter-current liquid extractor
only one of the liquids may be pumped at any desired rate.
A coalescer in a mixer-settler liquid-liquid extraction column
a. comprises of thin bed of substances of extended surface
having high porosity.
b. helps in increasing the bubble size entering the settler.
c. helps in increasing the settling rate of the bubbles.
d. all of these
all of these
Antibiotics are best handled in a
a. Podbielniak extractor
b. rotating disc contactor
c. sieve tray contractor
d. pulsed column extractor
Podbielniak extractor
Which of the following solutions will follow Raoult’s law most
closely?
a. A solution of benzene, toluene and oxylene
b. 35% solution of camphor in water
c. 35% solution of NH3 in water
d. A solution of polar organic compounds (not of homologs of a
series).
a. A solution of benzene, toluene and oxylene
Boiling point diagram is
a. not affected by pressure.
b. affected by pressure.
c. a plot of temperature vs. liquid composition.
d. a plot of temperature vs. vapor composition.
b. affected by pressure.
- The ease of difficulty of separating components by distillation is
determined by the
a. relative volatility
b. viscosity
c. mole fraction
d. weight fraction of the components
a. relative volatility
Strictly speaking, the relative volatility of most ideal binary
solution is
a. not affected by temperature
b. greatly affected by temperature
c. slightly affected by temperature
d. greatly affected by pressure
c. slightly affected by temperature
When the relative volatility of two miscible components is close to 1.00, the components can be separated by _____
c. extractive distillation
Distillation used for multicomponent systems like crude refining
Flash Distillation
The physical separation of components in a miscible mixture by simultaneous evaporation and condensation is
a. absorption
b. drying
c. extraction
d. distillation
d. distillation
In a batch distillation, the boiling point of the distillate product compared to the residue is
a. the same
b. higher
c. lower
d. half
c. lower
The temperature ____ as we go up the distillation column
decreases
The section below the feed plate is called
Stripping section
Operating line that always lies below the equilibrium curve
stripping section
In a packed column, channeling is prevented by which of the following equipment?
Liquid distributor
Increasing the operating pressure of a distilling column
a. does not make a difference in components separation
b. makes separation difficult
c. sharpens separation
d. requires less heat in the feed heater
b. makes separation difficult
One mole feed of a binary mixture of a given composition is flash vaporized at a fixed P and T. If Raoult’s law is obeyed, then changing the feed composition would effect
a. the product composition but not the fraction vaporized.
b. the product composition as well as the fraction vaporized.
c. the fraction vaporized but not the product composition.
d. neither the product composition nor the fraction vaporized.
C. The fraction vaporised but not the product composition
Steam distillation is used to
a. reduce the number of plates.
b. avoid thermal decomposition of a component.
c. increase the efficiency of separation.
d. increase the total pressure of distillation.
b. avoid thermal decomposition of a component.
The amount of steam required per unit quantity of distillate in case of steam distillation will be reduced by
a. raising the temperature
b. lowering the total pressure
c. both (a) and (b)
d. neither (a) nor (b)
c. both (a) and (b)
In distillation, the cooled liquid stream returned to the column to a cool plate or stage is called
a. reboil
b. reflux
c. feed
d. bottoms
b. reflux
In a distilling column, the highest pressure will be at
a. the top
b. the bottom
c. the feed plate
d. between the feed plate and the top
b. the bottom
A heat transfer equipment to convert vapor to liquid is a/an
a. evaporator
b. reboiler
c.condenser
d. still
c.condenser
A reboiler provides heat to the
a. top
b. the feed
c. the intermediate reflux
d. the bottom of a distilling column
d. the bottom of a distilling column
The temperature in distilling column, from bottom to top
a. increases
b. maximum
c. decreases
d. between minimum & maximum
a. decreases
The theoretical minimum reflux ratio in distillation column is
attained if the column has
a. 1 plate
b. 10 plates
c. 100 plates
d. infinite number of plates
d. infinite number of plates
If x co-ordinate of intersection point of feed line and rectifying sections operating line on equilibrium curve is same as the mole fraction of more volatile components in the feed, then the quality of feed is
a. subcooled liquid
b. saturated vapor
c. saturated liquid
d. superheated vapor
c. saturated liquid
As the reflux ratio decreases, the
a. separation becomes more efficient.
b. number of plates increases.
c. column diameter increases.
d. none of these.
number of plates increases.
In a distillation column, with increase in the reflux ratio, the heat
removed in the cooler _____
increases
Fenske’s equation for determining the minimum number of theoretical stages in distillation column holds good, when the ____
relative volatility is reasonably constant.
Inside the distillation column, the ____
a. driving force for the vapor flow is the pressure drop.
b. liquids are not always at their bubble points.
c. pressure increases gradually from bottom to the top of the column.
d. none of these
driving force for the vapor flow is the pressure drop.
On moving the feed line (q-line) from saturated liquid feed (vertical position) to saturated vapor feed (horizontal feed), if the slope of both the operating lines are to be increased, then it will result in ___
increased reflux ratio
In case of binary distillation, increasing the reflux ratio above optimum does not result in the increase of _____
area between operating line and 45° diagonal x-y diagram
Overall efficiency of the distillation column is equal to ____
the ratio of number of ideal plates to actual plates
Design calculation for multiple component distillation is done by ____
tray to tray calculations
Pick out the wrong statement:
a. Reboiler is not used in open steam distillation.
b. The separation of solutes of different molecular sizes in a liquid solution by use of a suitable membrane is called dialysis.
c. Freeze drying is used for the drying of fish.
d. Fenske-Underwood equation is used for calculating theoretical number of plates in a distillation column at normal operating reflux
condition.
Fenske-Underwood equation is used for calculating theoretical number of plates in a distillation column at normal operating reflux
condition.
In extractive distillation, solvent is used to ____
added to alter the relative volatility of the mixture.
In case of __________ distillation, a solvent is added to alter the relative volatility of the mixture to be separated.
Extractive
Solvent used in extractive distillation forms ____
forms a low boiling azeotrope.
Pick out the wrong statement.
a. Critical moisture content is not a property of the material itself.
b. A sharp increase in pressure drop gives an indication of the flooding in a distillation column.
c. Separation of components is not possible in liquid extraction, if selectivity is unity.
d. Dehydration of ethyl alcohol is most economically done by molecular distillation at very high vacuum.
Dehydration of ethyl alcohol is most economically done by molecular distillation at very high vacuum.
The equilibrium liquid composition compared to the vapor composition in case of azeotropic mixture is
same
(SAME AND ISASAGOT HINDI EQUAL)
Pick out the wrong statement.
a. The mole fraction of solute is directly proportional to the molality of a ‘dilute’ solution.
b. For a non-reacting binary mixture of ideal gases, the partial pressure distribution of both components is nonlinear in the case of steady state unimolal unidirectional diffusion.
c. Azeotropes obey Raoult’s law at all temperature.
d. The relative volatility of a binary mixture at the azeotropic composition is 1.
Azeotropes obey Raoult’s law at all temperature.
Azeotropic distillation is employed to separate ____.
constant boiling mixture
Pick out the system with minimum boiling azeotrope at 1 atm.
A. Benzene-toluene
B. Ethyl alcohol-water
C. Hydrochloric acid-water
D. All of the above
Ethyl alcohol-water
Which of the following binary systems is an example of a maximum boiling azeotrope?
A. Water-hydrochloric acid
B. Acetone-carbon disulphide
C. Water-ethyl alcohol
D. N-heptane-n-octane
Water-hydrochloric acid
Ponchan-Savarit method analyses the fractional equipment based on
enthalpy and material balances
This phenomenon occurs in a fluid flow system when the local static pressure drops below the vapor pressure of the liquid at
the existing temperature, resulting to damage to pumps and control valves from the formation of “bubbles” or voids.
Cavitation
It is a membrane separation process where a component from a heated liquid phase permeates through the membrane and is removed under low pressure.
Pervaporation
A process where components are separated from each other using a semi-permeable membrane by virtue of their different diffusion rates through the membrane is referred to as
Dialysis
Floating head heat exchangers are used for
cases where temperature difference between the shell and the tubes is more
(>50 C)
In double pipe (concentric heat exchanger), the hydraulic radius for heat transfer (for a fluid flowing through the annulus) would be ___
more than that for fluid flow
Oxygen %wt in atmospheric is
23
Preheating of gaseous fuel results in increased
Flame Temperature
Production of sulfuric acid based on oxidation of sulfur to sulfur trioxide on a vanadium oxide catalyst
Contact Process
A disproportionation reaction of two aldehyde molecules to give an alcohol and a carboxylic acid
Canizzaro reaction
It is the solid , cellular, infusible material remaining after the carbonization of coal, pitch, petroleum residue and certain other carbonaceous materials.
coke
Inorganic residue that remains after the coal has been burned. Composed of silicon, aluminum, iron and Calcium. Also, compounds of magnesium, sodium, potassium and titanium are also present in minor amounts.
Ash
It is the portion of the coal which when heated ion the absence of air under prescribed conditions is liberated as gases or vapors
volatile matter
The gas generated by blasting a deep, hot bed of coal or coke continuously with a mixture of air and steam
producer gas
A mixture of hydrogen and carbon monoxide produced by the reaction of water and carbon (coke) that is used as a starting point in the synthesis of methanol and other organic chemicals
Synthesis gas
It converts solar energy into electricity directly
photovoltaic cell