chapter 9 Flashcards
what is enthalpy?
measure of heat energy present in a chemical system
what is enthalpy change?
amount of energy released/taken in during a chemical reaction
what are the standard conditions?
1 atmosphere (100kPa)
298K (25 degrees)
1 mold dm cubed
what does it mean if an element is in its standard state?
its physical state of a substance under standard conditions
what is the standard enthalpy change for a reaction (r)?
enthalpy change that accompanies a reaction in the molar quantities shown in a chemical reaction under standard conditions
what is the standard enthalpy change of combustion (c)?
enthalpy change that occurs when 1 mole of a substance is burned completely in oxygen under standard conditions
what is the standard enthalpy change of formation (f)?
enthalpy change that occurs when 1 mole of a compound is formed from its elements under standard conditions
what is the standard enthalpy change of neutralisation (neut)?
enthalpy change that accompanies the reaction of an acid by a base to form 1 mole of H2O under standard conditions
what is the equation for energy transferred (q)?
q = mc change T
IN JOULES
how do you calculate enthalpy change?
calculate q (energy transferred)
calculate moles of fuel burned (excess)
q/moles
what is hess’ law?
shows that enthalpy change is independent to route
what do you do when you have combustion data for an enthalpy cycle?
use the combustion data
arrows go DOWN to CO2 and H2O
you are finding out the enthalpy change of formation
what do you do when you have formation data for an enthalpy cycle?
use the formation data
arrows UP
elements at the bottom
you are finding out the enthalpy change of combustion