Chapter 17 Flashcards

1
Q

Are carboxylic acids, esters, and amides all polar?

A

Yes

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2
Q

Can carboxylic acids, esters, and amides all hydrogen bond?

A

No, carboxylic acids and amides are able too

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3
Q

What are the most common carboxylic acids?

A

Acetic acid and citric acid

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4
Q

How are dioic acids different from carboxylic acids?

A

They have two -COOH groups

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5
Q

What can carboxylic acids do that ketones and aldehydes cannot?

A

Substitution reactions

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6
Q

_____ is made when there is a carbonyl group substitution reaction. To reverse it you need a ______ reaction

A

Esters
Hydrolysis

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7
Q

What is the most significant property of carboxylic acids?

A

They can surrender the H of their carboxyl group to bases and establish acid base equilibrium in aqueous solutions

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8
Q

T or F

Carboxylic acids cannot hydrogen bond with each other

A

False, they can

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9
Q

_____ straight _____ carbon chains are volitile liquids with pungent and unpleasant odors

A

Saturated
9

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10
Q

Carboxylic acids with up to ____ carbons are water soluble

A

4

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11
Q

The longer the carbon chain the lower or higher the melting/boiling point?

A

Higher

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12
Q

Carboxylic acids with more than ____ in their carbon chain are waxy odorless solids

A

9

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13
Q

What is the simplest carboxylic acid?

A

Formic acid

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14
Q

Can esters hydrogen bond with each other and water?

A

Not each other but can with water

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15
Q

T or F
Esters have higher boiling point than carboxylic acids

A

False

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16
Q

____ are colorless, volatile liquids with pleasant odors

A

Esters

17
Q

Are esters soluble in water? Are the flammable?

A

Somewhat soluble
Very flammable

18
Q

T or F
Esters are bases in aqueous solutions

A

False, neither acids nor bases in aqueous solutions

19
Q

Can amides hydrogen bond with each other?

A

1 degree= yes
2 degree=yes
3 degree=no

20
Q

Do amides have a higher boiling point than carboxylic acids?

A

Yes because they can hydrogen bond to each other

21
Q

_____amides are solids, soluble in water, and organic solvents

A

Unsubstituted
(Except formamide is a liquid)

22
Q

2 degree amides are also called what?

A

Mono-substituted

23
Q

3 degree amides are also referred to ____

A

Disubstiutued