Acids, bases and Kw Flashcards

1
Q

What are bronsted-lowry acids?

A

Proton donors

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2
Q

What are bronsted-lowry bases?

A

Proton acceptors

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3
Q

What does BAAD stand for?

A

Base
Acceptor
Acid
Donor

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4
Q

What do strong acids do in water?

A

Completely dissociate

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5
Q

What do weak acids do in water?

A

Partly dissociate

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6
Q

What is an example of a strong acid dissociating?

A

HCl -> H+ + Cl-

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7
Q

What is an example of a weak acid dissociating?

A

CH3COOH CH3COO- + H+

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8
Q

What do strong bases do in water?

A

Almost completely ionise

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9
Q

What do weak bases do in water?

A

Partially ionise

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10
Q

What is an example of a weak base ionising?

A

NH3 + H2O NH4+ + OH-

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11
Q

What is an example of a strong base ionising?

A

NaOH Na+ + OH-

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12
Q

Where does the equilibrium lie with strong acids and bases in water?

A

Far right

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13
Q

Where does the equilibrium lie with weak acids and bases in water?

A

Far left

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14
Q

Where does an acid put its protons?

A

Donates them to a base

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15
Q

What is the equation for the ionic product of water?

A

Kw = [H+][OH-]

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16
Q

What is the equation for the ionic product of pure water?

A

Kw = [H+]²

17
Q

Why is the equation for the ionic product of pure water different to the ionic product of water?

A

In pure water, there is always one H+ ion for every OH- ion

18
Q

Why doesn’t the expression for Kw include the concentration of water?

A

The concentration of H2O is so high compared to the concentration of [H+] and [OH-] and therefore it is effectively constant and doesn’t need to be included in the expression

19
Q

Why does the value of Kw increase with temperature increasing?

A

Dissociation is endothermic so therefore the equilibrium moves to the right hand side to absorb heat