6.3 The Laws of Thermodynamics Flashcards
all processes in a cell including a transfer or transformation in energy are subject to:
the laws of thermodynamics
first law of thermodynamics
the law of conservation of energy: Energy can neither be created nor destroyed-it can only be transformed from one form into another
when energy is transformed from one form to another, according to the first law of thermodynamics:
the total amount of energy remains the same
when energy changes forms….
the total amount of energy remains constant
in changing from one form of energy to another….
the energy available to do work decreases (some of the energy is available to do work and some is not available)
energy transformations are never 100% efficient since:
the amount of energy available to do work decreases every time energy changes forms-energy, often in the form of heat is released and used to increase entropy
the energy that is not available to do work takes the form of :
an increase in disorder
second law of thermodynamics
the principle that the transformation of energy is associated with an increase in the degree of disorder in the universe
entropy (S)
the degree of disorder in the system
microstates (synonymous with entropy)
the number of possible motions and positions of a molecule in any given system
in chemical reactions, most of the entropy increase occurs through:
the transformation of various forms of energy into thermal energy (heat)
thermal energy is:
a type of kinetic energy; the random motion of molecules that results in increased temperature
what is the correlation between temperature and disorder?
the higher the temperature, the more rapid the molecule movement and the higher the disorder
the amount of chemical potential energy expended is equal to:
the amount of kinetic energy plus the amount of thermal energy
catabolic reactions result in:
an increase in entropy as a single ordered biomolecule is broken down into several smaller ones with more freedom to move around