4/28 Flashcards

1
Q

for polar molecules, which modes of vibration are IR active?

A

all modes of vibrations are IR active because the dipole changes

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2
Q

for nonpolar modes of vibration, which are IR active and inactive?

A

the symmetric stretches are IR inactive
the asymmetric stretches and bending motions are IR active

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3
Q

for CO2 why do we only see 2 peaks instead of 4?

A

only 3 of the 4 peaks are IR active, two of the peaks, bending motions are equivalent in energy and overlap at the same peak

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