4/28 Flashcards
1
Q
for polar molecules, which modes of vibration are IR active?
A
all modes of vibrations are IR active because the dipole changes
2
Q
for nonpolar modes of vibration, which are IR active and inactive?
A
the symmetric stretches are IR inactive
the asymmetric stretches and bending motions are IR active
3
Q
for CO2 why do we only see 2 peaks instead of 4?
A
only 3 of the 4 peaks are IR active, two of the peaks, bending motions are equivalent in energy and overlap at the same peak