2/12 entropy Flashcards
∆S is what type of function
state
what is entropy a measure of
measure of disorder
for an isolated system, ∆S < 0 is
non spontaneous
for isolated systems, ∆S > 0 is
spontaneous
for decreases in temperature, ∆S is
∆S < 0, decreases
for increases in temperature, ∆S is
∆S > 0, increases as molecules move faster
for vaporization, ∆S is
∆S>0, liquid to gas
for melting, ∆S is
∆S>0, solid to liquid
for deposition (g->s) ∆S is
∆S <0, gas to solid
for chemical reactions, how does the entropy depend on the moles?
it depends on the moles of gas.
if the moles of gas increases, then ∆S>0
if the moles of gas decreases, then ∆S<0
what is the third law of thermodynamics
the absolute entropy of a perfectly crystalline substance at 0K is zero
for elements in their standard state at 25C, is their entropy zero?
no, it is a nonzero value. The only time it is zero is at 0 Kelvin