1/29 Work Flashcards

1
Q

for compression work, what is doing the work and what is the sign

A

the work is positive since work is being done on the system by the surroundings

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2
Q

for expansion work, what is doing the work and what is the sign

A

the work is negative because the system is doing work on the surroundings

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3
Q

what is irreversible work

A

irreversible work is done all in one step

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4
Q

if a piston is slammed rapidly to its final volume in one step, what type of work is it

A

it is irreversible

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5
Q

what is reversible work

A

work is done infinitesimally slowly

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6
Q

in reversible work, what is happening to the external pressure and pressure of the gas

A

the external pressure and gas pressures are constantly changing, the external pressure is infinitesimally larger than the gas pressure

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7
Q

in the derivation of the irreversible work equation, why can we assume the pressure is constant and pull it out of the equation

A

we assume it is constant because the work is done with one big external pressure

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8
Q

for reversible work, why can we exchange the Pexternal for the Pgas

A

the external pressure is infinitesimally larger than the gas pressure, but it is essentially equal to it

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9
Q

under what conditions can we use the reversible work equation

A

when the temperature is constant, isothermal

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10
Q

if the volume is constant, what is the work

A

it is zero

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11
Q

when dealing with a PV diagram, how do we calculate the work

A

treat the two paths as different work equations and subtract the second path from the first

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