1/29 Work Flashcards
for compression work, what is doing the work and what is the sign
the work is positive since work is being done on the system by the surroundings
for expansion work, what is doing the work and what is the sign
the work is negative because the system is doing work on the surroundings
what is irreversible work
irreversible work is done all in one step
if a piston is slammed rapidly to its final volume in one step, what type of work is it
it is irreversible
what is reversible work
work is done infinitesimally slowly
in reversible work, what is happening to the external pressure and pressure of the gas
the external pressure and gas pressures are constantly changing, the external pressure is infinitesimally larger than the gas pressure
in the derivation of the irreversible work equation, why can we assume the pressure is constant and pull it out of the equation
we assume it is constant because the work is done with one big external pressure
for reversible work, why can we exchange the Pexternal for the Pgas
the external pressure is infinitesimally larger than the gas pressure, but it is essentially equal to it
under what conditions can we use the reversible work equation
when the temperature is constant, isothermal
if the volume is constant, what is the work
it is zero
when dealing with a PV diagram, how do we calculate the work
treat the two paths as different work equations and subtract the second path from the first