Year 11 Term 1 Flashcards

1
Q

What’s an exothermic reaction

A

One that gives out energy to the surroundings when bonds are formed

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2
Q

What’s an endothermic reaction

A

One that takes in energy from the surroundings and breaks bonds

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3
Q

What happens during a chemical reaction

A

Bonds are broken, atoms are rearranged and then bonds are reformed

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4
Q

Energy in a chemical reaction

A

Energy never created or destroyed so total amount of energy after reaction is the same as before

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5
Q

How do we know if it’s an exothermic reaction

A

If the energy of the product is lower than the reactants then energy has been released

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6
Q

How do we know if it’s an endothermic reaction

A

If the energy of the products is higher than the reactants then the energy has been taken in

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7
Q

How is hydrogen gas used in hydrogen fuel cells

A

Supplied to as a fuel to the cathode. diffuses through graphite electrode and reacts with hydroxide ions to form water and provides electrons to an external circuit

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8
Q

How is oxygen gas used in hydrogen fuel cells

A

Supplied to anode. diffuses through graphite and reacts to form hydroxide ions, accepting ions from the external circuit

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9
Q

What happens if you add the two electrons together

A

The electrons and the hydroxide ions on either side of the half equations cancel out so left with overall charge in the hydrogen fuel cell, that is the oxidation of hydrogen (the fuel)

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10
Q

Advantages of hydrogen fuel cells

A

Don’t need to be electrically recharged
No pollutants are produced
Can be a range of sizes for different uses

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11
Q

Disadvantages of hydrogen fuel cells

A

Hydrogen is highly flammable
Hydrogen sometimes produced for the cells by non-renewable sources
Hydrogen is difficult to store

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12
Q

Fuel cells are also useful as a potential energy source for space craft as:

A

They provide water
They are very efficient
They have no moving parts
They are lightweight

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13
Q

Functional group

A

The part of the molecule responsible for reactions

The functional group of alkenes is the double bonds

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14
Q

Homologous series

A

A series of compounds that have similar properties + same general formula

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15
Q

Combustion of Alkenes

A

Burn with a smokier, yellower flame (compared to alkanes)
Incomplete combustion
releases less energy per mole in combustion than alkanes

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16
Q

Alkane + Bromine water =

A

No reaction

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17
Q

Alkene + Bromine water =

A

Turns colourless

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18
Q

Why does the C=C bond in alkenes makes them more reactive than alkanes

A

Because the C=C is electron dense
the double bond can open up and other molecules can react with the carbons, ‘add’ to the alkene
these are addition reactions

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19
Q

What is hydrogenation and what conditions are needed for it to occur

A

Adding hydrogen to unsaturated alkenes, making them saturated alkanes
60*C
Nickel catalyst

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20
Q

Why would we want to turn alkene into alkane

A

Straighten the molecules
increase melting point
e.g. to make margarine (enough hydrogen to make it spreadable from the fridge (not too solid) but not too much that it’s a liquid)

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21
Q

Advantages of hydrogenation

A

As now solid, can be used as a spread

More useful

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22
Q

Disadvantages of hydrogenation

A

Saturated fats not healthy option, as the molecules pack closely together, making it harder for body to break it down

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23
Q

What is hydration and what conditions are needed

A

It’s the addition of water, it’s reversible so ethanol can break down into steam and ethene. unreacted ethene and steam are recycled over the catalyst
Concentrated phosphoric acid catalyst
High temp and pressure

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24
Q

In all addition reactions…

A

Only one molecule of halogen, hydrogen or water is needed as only one double bond to open up

25
Q

Halogens and hydrogen

A

One bromine from bromine molecule bonds to one carbon from the double bond, then the other Br bonds to the other carbon from the double bond
Hydrogen the same but with H-H

26
Q

Water

A

H bonds to one of the carbons, then OH bonds to the others

27
Q

How does fermentation work

A

Extract sugar (glucose) from crops
Add yeast to glucose (enzymes in yeast act as catalyst)
Fermentation - 30-40*C, CO2 released

28
Q

Advantages of fermentation

A

Sugars (renewable source)
batch process is cheap so is the equiptment needed
more carbon neutral

29
Q

Disadvantages of fermentation

A

Very slow
very impure- needs further processing which takes time and money
Batch process (stop and start) so high labour cost

30
Q

How does hydration of ethene work

A

Extract crude oil from the ground
oil refinery - fractional distillation then cracking to get ethene
Hydration- phosphoric acid catalyst, high temp and pressure, continuous process

31
Q

Advantages of hydration

A

Fast reaction
Pure product
95% yield
continuous (cheaper manpower)

32
Q

Disadvantages of hydration

A

High technology equiptment needed- expensive initial cost
high energy costs for high pressure
ethene is non-renewable

33
Q

What are carboxylic acids

A

Carboxylics are a homologous series with the functional group COOH

34
Q

Molecular formula for methanoic acid

A

HCOOH

35
Q

Molecular formula for ethanoic acid

A

CH3COOH

36
Q

Molecular formula for propanoic acid

A

C2H5COOH

37
Q

Molecular formula for butanoic acid

A

C3H7COOH

38
Q

What happens when ethanoic acid dissolves in water

A

The pH decreases, turning the universal indicator red

39
Q

What happens when ethanoic acid reacts with a metal carbonate

A

Salt, carbon dioxide and water produced

40
Q

How is an ester bond formed

A

When a carboxylic acid reacts with alcohol

41
Q

What are esters

A

Chemicals with pleasant smells. They are used in perfumes and as solvents

42
Q

Ethanoic acid + ethanol

A

ethylethanoate + water

43
Q

Are carboxylic acids strong or weak acids

A

Weak acids as they don’t completely ionise in when dissolved in water. Instead only some of their molecules ionise to form H+ ions

44
Q

What is condensation polymerisation

A

Involves monomers with two functional groups reacting, joining together usually losing small molecules such as water

45
Q

What are the simplest condensation polymers produced from

A

Two different monomers with two of the same functional groups

46
Q

What do most condensation reactions form

A

Either an ester bond or and amide bond

47
Q

What are amide bonds between

A

Between carboxylic acids and amines

48
Q

Where are the new bonds in condensation polymerisation usually

A

Where the functional groups are located

49
Q

Functional groups of alcohols

A

-OH

50
Q

Functional groups of Amine

A

-NH2

51
Q

Difference between addition polymers and condensation polymerisation

A

In addition, monomers form together and no other substance is formed but in condensation another small molecule, often water is given off

52
Q

What is the structure of amino acids

A

An amine group on one end and a carboxylic acid on the other

53
Q

How are proteins made

A

Amino acids form polymers know as polypeptides via condensation polymerisation.
One or more long chains of polypeptides are known as proteins

54
Q

What are proteins used for in the body

A

Enzymes used as catalysts, haemoglobin transports oxygen, antibodies form part of immune system etc

55
Q

What does DNA stand for

A

Deoxyribonucleic acid

56
Q

What is DNA

A

Encodes genetic instructions for the development and functioning of living organisms and viruses

57
Q

What is the formation of DNA

A

DNA molecules are two polymer chains, made from 4 different monomers called nucleotides in the form of a double helix

58
Q

What are sugars

A

Small molecules that contain carbon, oxygen and hydrogen

59
Q

What happens when sugar reacts through polymerisation

A

They form larger carbohydrate polymers e.g. starch which living things use to store energy, and cellulose which is found in plant walls