Week 8 - Material Properties 2 Flashcards

1
Q

What is specific heat (Cp)

A

the heart energy required to increase the temperature of a unit volume by 1 degrees

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2
Q

What is thermal conductivity (K)

A

the rate of transportation of heat (cal or J) through material per unit temperature gradient

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3
Q

What is thermal diffusivity (h)

A

the rate at which heat spreads through a material. It indicates how quickly a material can conduct thermal energy relative to how much it can store. In other words, thermal diffusivity reflects how fast temperature changes in a material when it is subjected to a thermal gradient.

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4
Q

What temperature can cause tooth pulp damage

A

increasing tooth pulp temperature 5.5 degrees or more

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5
Q

What is coefficient of thermal expansion

A

the fractional increase in the dimension of a body as a function of increased temperature. = the extent to which a material expands or contracts when its temperature changes. It describes how much of a material size will change per degree change in temperature.

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6
Q

the expansion and contraction of dental materials is a function of what

A
  • thermal diffusivity
  • coefficient of thermal expansion
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7
Q

what type of degradation occurs in metals

A
  • tarnish
  • Corrosion
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8
Q

What type of degradation occurs in polymers

A
  • Chain scission
  • Absorption/adsorption
  • dissolution
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9
Q

What type of degradation occurs in ceramics

A
  • hydrolytic attack
  • Dissolution
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10
Q

What is tarnish

A

the surface discolouration due to the formation of soft and hard surface deposits. E.g. sulphides and chlorides

  • when a thin layer of corrosion forms on the surface of a metal due to a chemical reaction with environmental elements, such as oxygen, sulfur or other compounds.
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11
Q

What is corrosion

A

a deterioration of a material by chemical reaction with its environment

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12
Q

what does corrosion of material properties lead to (3)

A
  • structural breakdown
  • leaching out cytotoxic or allergic elements
  • tissue discolouration
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13
Q

What are the different types of corrosion

A
  1. chemical corrosion

a. dry corrosion

b. wet corrosion

  1. Stress corrosion (chemical + mechanical)
  2. Galvanic corrosion
  3. Concentration cell corrosion (surface roughness or deep pit and fissures)
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14
Q

What is dry corrosion

A

Dry corrosion is a type of corrosion that occurs in the absence of moisture, typically when metals react directly with gases in the environment (such as oxygen) at elevated temperatures.

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15
Q

What is an example of dry corrosion

A

The reaction where iron reacts with oxygen at high temperature to form iron oxide (Fe2O3) is a common example (rusting)

This process forms an unstable oxide surface which will flake off and corrosion will continue. however this process is self limiting in some metals where a stable surface oxide forms e.g. chromium oxide on stainless steel.

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16
Q

What is wet corrosion

A

Wet corrosion is a type of corrosion that occurs when metals are exposed to moisture (water or an electrolyte solution) and undergo a chemical reaction. This process typically involves both an oxidation and reduction reaction and requires the presence of water or another electrolyte, along with oxygen or other corrosive agents.

17
Q

Where does corrosion occur

A

Corrosion occurs in the Anode where an electro negative metals are placed in an electrolyte

18
Q

What is galvanic corrosion

A

galvanic corrosion occurs when two dissimilar metals are connected by an electrolyte, leading to the accelerated corrosion of one metal (the more anodic) while the other metal (the more cathodic) is protected.

19
Q

What is an example of galvanic corrosion

A

Pt and An

20
Q

what is crevice corrosion

A

Crevice corrosion is a localized form of corrosion that occurs in a sharp crack or fluid filled space . the confined nature of the space allows corrosive agents (such as moisture or salt) to become trapped and concentrate, leading to accelerated corrosion in these areas.

21
Q

What are the consequences of corrosion in the mouth (5)

A
  • pain due to galvanic effect
  • metallic taste due to the release of ions
  • Deterioration in appearance and mechanical properties
  • increased body burden of metallic ions such as nickel and mercury
  • Tissue discolouration of hard and soft tissue
22
Q

What are methods to eliminate corrosion

A
  • Homogenizing treatment of alloys eliminates the possibility of chemical corrosion in metals
  • Finishing and polishing the surfaces of restoration can eliminate crevice corrosion
  • Avoiding close contact between dissimilar metals in the mouth to avoid galvanic effects of corrosion