Week 8 - Dental Amalgam Flashcards
What is the composition of conventional amalgam
alloy powder + triple distilled mercury
What is the composition of the alloy powder
Silver 67-74%
Tin 25-27%
Copper <6%
Zinc 2-5%
What is the amalgam setting reaction
What is y phase (gamma phase)
the primary phase formed during the setting of dental amalgam. It consists mainly of silver tin alloy (Ag3Sn) and is responsible for most of the amalgam’s strength and durability. the y phase is the least prone to corrosion and is essential for the mechanical properties of the amalgam
what is the tensile strength of y phase
170 MPa
What is y1 phase (gamma 1 phase)
A silver mercury alloy Ag2Hg3. It is formed when the mercury reacts with the silver present in the amalgam
What are the properties of y1 phase
- provides some tensile strength (more than y2 but less than y)
- more susceptible to corrosion than the y phase
What is the tensile strength of y1 phase
30 MPa
What is y2 phase (gamma 2 phase)
A tin mercury alloy (Sn8Hg).
What are the properties of y2 phase
- weakest tensile strength
- most corrosion prone
- lead to degradation of the amalgam over time
- cause high creep resulting in ditching
what is the tensile strength of y2 phase
20 MPa
What do you do to reduce the amount of y2 phase in amalgam
Increase Copper content: high copper amalgams
Adding Cu = 10-30%
- In high copper amalgams some of the tin reacts with copper instead of mercury, forming the y phase (gamma 1) which is more stable and less prone to corrosion. this substitution reduces the formation of y2 phase.
What are the dimensional changes during the setting reaction of amalgam
- Primary contraction - slight contraction as amalgam particles react with mercury
- Expansion - due to formation of the y phase
- Delayed expansion (only occurs sometimes)
What causes delayed expansion
Amalgams that contain zinc can react with moisture (especially in the presence of saliva or other fluids) after they have set. This reaction can lead to the formation of zinc hydroxide and hydrogen gas, contributing to an increase in volume.
What is dimensional changes of amalgam depend on
- type of alloy
- particle shape and size
- manipulative variables