Week 7 - GIC Flashcards
What is the normal composition of GIC
Powder
- fluoro-alumino-silicate glass
- Na alumino-silicate glass
- CaF
- Pigments
Liquid
- polyacrylic + maleic or itaconic acid
- tartaric acid
- distilled water
What is the function of tartaric acid in GIC
- Improves working time and reduces setting time
- leads to improved mechanical properties
- interacts with the polyacid and glass particles promoting the release of ions like calcium and aluminum
What is the function of Maleic acid and Itaconic acid
- enhances the adhesive properties of the glass ionomer cement by increasing the number of carboxylic and acid groups available for bonding with the tooth surface
- creates a denser cross linked network with the cement matrix leading to improved compressive, tensile and flexural strength
What is the function of water in GIC
to activate the acids - creates an aqueous solution
What is the main process/es in GIC setting
Acid Base reaction and crosslinking and gelation
What is the GIC chemical process
- Mixing - polyacrylic acid dissolves the fluoro-alumino-silicate glass
- Acid-base reaction - acid reacts with glass particles releasing Ca, Al, Na, F ions
- Cross linking and setting - Ca reacts with polyacrylic chain (gelation) forming a loosely bound gel like network. Ca continue to cross link with the carboxylate groups on the polyacrylic acid forming a matrix that starts to harden
- Maturation - after 24h AL gradually reacts with the carboxylate groups, leading to further cross linking and hardening, significantly increasing the strength of the cement
What can GIC bond to
dentin and enamel
what does GIC bond to calcium apatite via
ionic bonds
What does GIC bond to collagen via
hydrogen bonds
What should be used to clean/condition surfaces for GIC
10-20% polyacrylic acid (or phosphoric acid by GC)
What is the impact of a GIC being compromised with moisture
- Aluminium ions may leach out due to contact with saliva resulting in poor mechanical strength
- contamination with saliva, blood and extra moisture will result in poor aesthetics (dull and white), strength and bonding
What happens if you over dry GIC
delays the setting reaction
What is a method to prevent moisture in the GIC
- careful isolation
- application of a protective cover such as varnish, GIC coat or light activated bonding agents for 24h
When can you use GIC
- Class 3, 5
- Class 1, 2 in deciduous teeth
- Fissure fillings (minimal class 1)
- Base/core-build-up
- Long term temporary restorations
- ART (atraumatic restorative treatment)
What are advantages of GIC
- Bulk placement
- Sustained release of fluoride
- Biocompatible
- Direct adhesion to enamel and dentine
- Less stained