Water Flashcards

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1
Q

Shape and structure of water molecule

A

Shaped like wide V
Two hydrogen atoms joined to an oxygen atoms by single covalent bond

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2
Q

Water molecule’s polarity

A

water is a polar molecule because oxygen is more electronegative than hydrogen so the shared pair of electrons pair spend more time near oxygen forming polar covalent bond

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3
Q

Overall charge of water molecule

A

Oxygen contains two regions of partial negative charge and hydrogen has a region of partial positive charge

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4
Q

Which type of bond is held two water molecules together?

A

Hydrogen bond

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5
Q

Six properties of water

A

1.Polarity
2.Excellent solvent
3.High heat capacity
4.Cohesion(high surface tension)
5.Adhesion
6.Low density when frozen

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6
Q

How water can be excellent solvent?

A

As water molecule is polar molecule,it can dissolve poler molecules and ions due to its ability to form ion-dipole and dipole-dipole interactions

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7
Q

What is cohesion?

A

Attraction between water molecules

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8
Q

What is adhesion?

A

Attraction between water molecules and other substances

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9
Q

What is surface tension?

A

A measure of how difficult it is to stretch or break the surface of a liquid

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10
Q

Why water molecules have high surface tension?

A

At the interface between water and air,water molecules are hydrogen-bonded to one another to water molecules below but not to the above air

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11
Q

What is kinetic energy?

A

The energy of motion

The faster a molecule moves,the greater its kinetic energy

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12
Q

What is thermal energy?

A

The kinetic energy associated with random movements of atoms and molecules

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13
Q

What is difference between thermal energy and temperature?

A

Thermal energy of a body of matter is the total kinetic energy that depends on matter’s volume

Temperature is the average kinetic energy of molecules in body without the volume of the body

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14
Q

What will happen when two objects with the different temperature are brought together?

A

Thermal energy passes from warmer objects to cooler object until the two are at the same temperature

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15
Q

What is heat?

A

Thermal energy in transfer from one body of matter to another

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16
Q

Units of heat

A

Calorie(cal)-amount of heat it takes to rise the temperature of 1g of water by 1 C
Kilocalorie(kcal)-1000cal-amount of heat required to raise the temperature of 1kg of water by 1•C
Joule

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17
Q

Specific heat

A

The amount of heat that must be absorbed or lost for 1g of substance to change its temperature by 1•C

A measure of how well a substance resists changing its temperature when it absorbs or releases heat

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18
Q

Water’s specific heat

A

1cal/(g •C) i.e.1 cal of heat is required for 1g of water to change its temperature by 1•C

water resists changing its temperature when it absorbs or releases heat

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19
Q

Water’s high specific energy compared to ethanol

A

Water-1cal/g•C
Ethanol-0.6cal/g•C

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20
Q

What is heat of vaporization?

A

The quantity of heat of a liquid must absorb for 1 g of liquid to be converted from liquid to gaseous state

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21
Q

Do water have high heat vaporization?

A

Yes

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22
Q

Density of ice vs liquid water

A

Ice has lower density than liquid water because of crystalline lattice structure of ice

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23
Q

What is water density at 4•C and above?

A

At 4•C,like other liquids water expands as it warms and water contracts as it cools

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24
Q

Water density at below 4•C-0•C

A

Water begins to freeze because more and more of its molecules are moving too slowly

At 0•C,the molecules is locked into crystalline lattice structure

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25
Q

what is solvent?

A

Dissolving agent of a solution

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26
Q

What is solute?

A

The substance that is dissolved in solution

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27
Q

What is solution?

A

A liquid that is completely homogeneous mixture of two or more substances

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28
Q

What is aqueous solution?

A

The solute is dissolved in water

water is the solvent in aqueous solution

29
Q

Which solutes can water dissolve?

A

Ionic molecules and polar molecules

30
Q

Hydrophilic molecules

A

Molecules that have affinity for water (ionic and polar molecules)

water-loving molecules

31
Q

All hydrophilic molecules are dissolved in water.True or false?

A

False,substances can be hydrophilic without actually dissolving

Eg.cotton

32
Q

Hydrophobic molecules

A

Substances that do not have an affinity for water (nonionic and non-polar molecules)

water-hating molecules

33
Q

What is molarity?

A

Molarity is the unit of concentration

The number of moles of solute per liter of solution

34
Q

What is mole?

A

A mole is a certain number of molecules of a substance.

35
Q

What is molecular mass?

A

The mass of a mole of substance in grams

36
Q

Water dissociation

A

When two water molecules are connected by a hydrogen bond ,hydrogen ions(H+) is transferred to one molecule to another forming Hydronium ions(H3O+) and the molecule that lost hydrogen ion becomes hydroxide ion(OH-)

It is the reversible reaction and reaches at a state of equilibrium

37
Q

What is the concentration of H+ and OH- in pure water?

A

same concentrations

38
Q

What is acid?

A

A substance that increases the hydrogen ion concentration of a solution

HCl——->H+ +Cl-

39
Q

What is base?

A

a substance that reduces the concentration of H+ ion

Some bases reduce H+ conc directly by accepting hydrogen ions and
other bases reduce reduce H+conc indirectly by dissociating to form OH- ions

40
Q

What is acidic solution?

A

Solution with higher concentration of H+ ions than OH- ions

acidic solution have pH value of less than 7

41
Q

What is basic solution?

A

A solution with higher concentration of OH- ions than H+ions

basic solutions have pH value of greater than 7

42
Q

How strong acid and strong base dissociate in water?

A

Completely dissociate

Eg.HCl and NaOH

43
Q

What is weak acid and weak base?

A

The substance that dissociates partially in water

44
Q

In which temperature,the product of [H+][OH-] concentration is constant?

A

25 degree Celcius

45
Q

In 25 degree Celcius,the product of [H+][OH-] concentration is constant.What is tha value of this constant?

A

[H+][OH-]=10 *-14

So [H+]=10* -7 and [OH-]=10* -7

46
Q

When enough acid is added to the solution to increase [H+] to 10*-5M ,what is [OH-] value?

A

10* -9 M

47
Q

When enough base is added to the solution to increase [OH-] to 10*-4M ,what is [H+] value?

A

10* -10 M

48
Q

pH and [H+] relation

A

pH=-log[H+]

pH decreases as H+ concentration increases

49
Q

pH 1 example

A

Battery acid

50
Q

pH 2 example

A

Gastric juice(HCl in stomach)
Lemon juice

51
Q

pH 3 example

A

Vinegar
Wine
Cola

52
Q

pH 4 and 5 example

A

Tomato juice
Beer
Black coffee

53
Q

pH 5.5 example

A

rain water

54
Q

pH 6 example

A

Urine

55
Q

pH 7 example

A

Saliva
Pure Water
Human blood
Tears

56
Q

pH 8 example

A

seawater
inside small intestine

57
Q

pH 10.5 example

A

Milk of magnesia

58
Q

pH 11.5 example

A

Household ammonia

59
Q

pH 13 example

A

Household bleach

60
Q

pH 13-14 example

A

Oven cleaner

61
Q

pH value of blood

A

7.4

62
Q

How strong acid effect on pH value of pure water?

A

if 0.01 mol of strong acid is added to 1L of pure water,pH drops from 7.0 to 2.0

63
Q

If 0.01mol of strong acid is added to 1L of blood,how the pH value change?

A

pH value decrease only 7.4 to 7.3

64
Q

Why does tha addition of strong acid of acid have so much less effect on pH of blood than it does on pH of pure water?

A

The presence of buffers in biological fluids to maintain constant pH despite the addition of acid or bases

65
Q

What is buffer?

A

a substance that minimizes changes in the concentration of H+ and OH- in a solution

Most buffer solutions are weak acid and its corresponding base,which combine reversibly with H+ ions
Eg.Carbonic acid H2CO3
Acetic acid CH3COOH

66
Q

How carbonic acid dissociate as buffer solution?

A

Carbonic acid dissociates into a bicarbonate ions(HCO3-) and hydrogen ions(H+)

The reaction is reversible and is in equilibrium state

67
Q

What will happen if the H+ concentration in blood begins to fall?

A

when [H+] fall in blood, pH of blood will rises

So more carbonic acid dissociates and replenishes H+ ions

68
Q

What will happen if the H+ concentration in blood begins to rise?

A

when [H+] rise tha pH of the blood drops

So HCO3- and H+ ions will react to form more carbonic acid(H2CO3)

69
Q

Is that correct most buffers are acid-base pairs?

A

Yes