Trends Periodic Table Flashcards
Most Reactive Chemical Groups
1 and 7
Period
Horizontal across periodic table. Elements similar chemical properties
Group Def.
Verticle periodic table
Metal Def.
Good conductor of heat/electricity
Non-metal def.
Poor conductor of heat/electricity
Metalloid Def.
Part metal, part non. Conductor of heat of standard between metal and non-metal
Effective Nuclear Force Depends On
No. of protons in nucleus, shielding effects of orbits closer to nucleus and distance from nucleus
Effective Nuclear Charge (Zeff)
Nuclear charge felt by an electron when both the effective nuclear charge and shielding effect into account
Zeff across period
Increases (as atomic number does and screening remains the same)
Zeff down group
Decreases (as screening increases)
Atomic Radius Def.
Half the distance between 2 nuclei if 2 adjacent atoms
Atomic Radius across period
Decreases
Atomic Radius down group
decreases
Ionic Radius Change during anion Formation
Increases. Additional electron causes others to be pushed outwards by repulsive force (nuclear charge in same)
Ionic Radius change during cation formation
Decreases. Electron removed causes force repelling electrons outwards to diminish
Ionic Radius of dipositive ions are smaller then Ionic radius of unipositive ions that are isoelectronic because…
Dipositive ion has bigger nuclear charge
Ionic radii of dinegative ions are bigger the isoelectronic uninegative ions because….
Uninegative has less screening = bigger nuclear charge
1st Ionisation Energy (kJ/mol)
Min. energy required to remove the outermost electron from a ground atom in gaseous state
Ionisation energy across period
Increases
Ionisation Energy down group
decreases
Electronegativity Def.
Ability of an atom to attract electrons towards itself in a chemical bond
Electron Affinity Def.
The negative energy change that occurs when an electron is accepted by a neutral gaseous atom
Relationship between electron affinity and atoms accepting electrons
Greater positive electron affinity, greater chance of accepting electron
Relationship between heat change and electron affinity
- x kJ/mol = + x kJ/mol
Why is F the most electronegative element
High nuclear charge, little shielding. High electron affinity and high ionization energy
Most electronegative elements
F > O > N > C