Importance of Free Energy in Biological Processes Flashcards
Favourable Reactions Def
Reactions occur to decrease the enrgy of the system. This is done in exothermic reactions moving towards disorder
Entropy Def
Measure of randomness (disorder). High entropy = low energy system. Temperature dependent (high temp = high entropy). Units K/J mol
Positive Delta S
Going from order to disorder
Negative Delta S
going from disorder to order
possitive delta H
endothermic
negative delta H
exothermic
Indicators of postive S
State change from solid->liquid-> gas, increasing temp and dissolution, increasing number of molecules
Indicators of negative delta S
State change gas->liquid-> solid, decreasing temp, precipitation, decreasing number of molecules
Gibbs Free Energy
Energy associated with a chemical reaction that is used to do work
Delta G
the amount of energy for a reaction at a constant temp
Negative delta G
Spontaneous Reaction
Positive delta G
Non-spontaneous reaction
Delta G Equation
Delta H - (Temp in K)(Delta S)
When delta S is negative (moves to order) how should the temp be to esure - delta G
Low. Negative delta S times a negative temp (equation) makes a positive.
What does temp need to be when reaction is endothermic and delta S is negative
high. Ensures negative delta G