Transports et équilibres ioniques Flashcards

1
Q

ions soumis à 2 forces

A

force motrice

force de résistance visqueuse (frottements)

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2
Q

force motrice

A

Fe = q.E = Z.e.E

Z: valence de l’ion

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3
Q

force de résistance visqueuse

A

Fr = -f.v

f: coefficient de friction
v: vitesse de déplacement de l’ion

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4
Q

coefficient de friction

A

f ≈ 6.π.η.r
η: index de viscosité
r: rayon de l’ion

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5
Q

vitesse d’un ion

A

v = Z.e/f . E = u x E

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6
Q

mobilité u d’un ion

A

correspond à sa capacité à être mobile indépendamment du champ électrique
u = Z.e/f ≈ Z.e/ 6πηr
u = v/E en m2.s-1.V-1
Z.e = q = charge

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7
Q

formule du courant électrique

A

I = m.F.S.v
m: molarité
F: Na x e (le Faraday)

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8
Q

loi de Nernst

A

V2-V1 = RT/zF . ln(m1/m2) (cations)

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