Thermodynamics Flashcards

Enthalpy change definitions

1
Q

What is the standard molar enthalpy of formation?

A

Enthalpy change when one mole of compound is formed from its constituent elements

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2
Q

What is enthalpy of combustion?

A

Enthalpy change when one mole of substance is completely burnt in oxygen

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3
Q

What is enthalpy of atomisation?

A

Accompanies the formation of one mole of gaseous atoms from the element in its standard state under standard conditions

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4
Q

What is the first ionisation energy?

A

Standard enthalpy change when one mole of gaseous atoms is converted into a mole of gaseous ions each with a single positive charge

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5
Q

What is second ionisation energy?

A

Loss of a mole of electrons from a mole of singly positively charged ions

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6
Q

What is first electron affinity

A

A mole of gaseous atoms is converted to a mole of gaseous ions each with a single negative charge

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7
Q

What is the second electron affinity?

A

One mole of electrons is added to a mole of gaseous ions each with a single negative charge to form ions each with 2 negative charges

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8
Q

Define lattice enthalpy of formation

A

One mole of solid ionic compound is formed from its gaseous ions

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9
Q

Define enthalpy of hydration

A

Water molecules surround one mole of gaseous ions

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10
Q

Define enthalpy of solution

A

One mole of solute dissolves completely in sufficient solvent to form a solution in which the molecules are far apart enough not to interact with each other

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11
Q

What is mean bond enthalpy?

A

One mole of gaseous molecules each breaks a covalent bond to form two free radicals, averaged over a range of compounds

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