Acids, bases and buffers Flashcards

1
Q

What is a Bronstead-Lowry acid?

A

A substance that can donate a proton.

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2
Q

What is a Bronstead-Lowry base?

A

A substance that can accept a proton.

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3
Q

Can H2O act as an acid or a base?

A

Both

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4
Q

What is the equilibrium expression for H2O?

A

Kc= [H][OH] / [H2O]

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5
Q

What is the ionic product of water?

A

Kw

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6
Q

What is the expression of Kw?

A

Kw = [H] [OH]

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7
Q

What is the expression for pH?

A

pH = -log [H]

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8
Q

Why does the value of Kw increase as the temperature increases?

A

Dissociation of water is endothermic. Increasing the temperature favours this direction so increases the value of Kw.

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9
Q

Why is water not acidic at a higher temperature?

A

Same concentrations of H and OH

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10
Q

Is an acid that fully dissociates strong or weak?

A

Strong

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11
Q

Is a base that partly dissociated strong or weak?

A

Weak

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12
Q

Do acids get stronger or weaker as the acid dissociation constant increases?

A

Stronger, the equilibrium is further right.

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13
Q

Write an expression for Ka.

A

Ka = [H] [A] / [HA]

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14
Q

Write an expression for Ka if the acid is weak and in aqueous solution.

A

Ka = [H]^2 / [HA]

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15
Q

What is the equivalence point?

A

The point at which sufficient base has been added to just neutralise the acid.

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16
Q

Is HCl a strong or weak acid?

A

Strong

17
Q

Is NaOH a strong or weak base?

A

Strong

18
Q

Is Ethanoic acid (CH3COOH) a strong or weak acid?

A

Weak

19
Q

Is NH3 a strong or weak base?

A

Weak

20
Q

How does the half-neutralisation point allow you to find the pKa of a weak acid?

A
ka = [H]
-log(Ka) = -log[H]
pKa = pH
21
Q

What is an acidic buffer made from?

A

A mixture of a weak acid and a soluble salt of that acid.