Acids, bases and buffers Flashcards
What is a Bronstead-Lowry acid?
A substance that can donate a proton.
What is a Bronstead-Lowry base?
A substance that can accept a proton.
Can H2O act as an acid or a base?
Both
What is the equilibrium expression for H2O?
Kc= [H][OH] / [H2O]
What is the ionic product of water?
Kw
What is the expression of Kw?
Kw = [H] [OH]
What is the expression for pH?
pH = -log [H]
Why does the value of Kw increase as the temperature increases?
Dissociation of water is endothermic. Increasing the temperature favours this direction so increases the value of Kw.
Why is water not acidic at a higher temperature?
Same concentrations of H and OH
Is an acid that fully dissociates strong or weak?
Strong
Is a base that partly dissociated strong or weak?
Weak
Do acids get stronger or weaker as the acid dissociation constant increases?
Stronger, the equilibrium is further right.
Write an expression for Ka.
Ka = [H] [A] / [HA]
Write an expression for Ka if the acid is weak and in aqueous solution.
Ka = [H]^2 / [HA]
What is the equivalence point?
The point at which sufficient base has been added to just neutralise the acid.
Is HCl a strong or weak acid?
Strong
Is NaOH a strong or weak base?
Strong
Is Ethanoic acid (CH3COOH) a strong or weak acid?
Weak
Is NH3 a strong or weak base?
Weak
How does the half-neutralisation point allow you to find the pKa of a weak acid?
ka = [H] -log(Ka) = -log[H] pKa = pH
What is an acidic buffer made from?
A mixture of a weak acid and a soluble salt of that acid.