Group 7 Flashcards

1
Q

Do halogens get more or less electronegative going down the group?

A

Less, due to shielding.

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2
Q

What sort of molecules do halogens exist as?

A

Diatomic.

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3
Q

Does boiling point increase or decrease going down the group and why?

A

Increases, number of electrons increase as the atoms get larger, increasing the van der Waals forces that act between molecules.

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4
Q

Does the oxidising ability of halogens increase or decrease down the group?

A

Decreases, ability to gain electrons is greater at the top of the period as less shielding.

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5
Q

What can fluorine oxidise?

A

Cl, Br and I

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6
Q

What can chlorine oxidise?

A

Br and I

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7
Q

What can Br oxidise?

A

I

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8
Q

What colour is Cl2?

A

Pale green.

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9
Q

What colour is Br2?

A

Orange

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10
Q

What colour is I2?

A

Brown

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11
Q

Does reducing ability increase or decrease down the group?

A

Increase, larger the ions, the more easily it loses it’s electrons due to shielding.

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12
Q

Why is no precipitate seen when fluorine is reacted with acidified silver nitrate?

A

Forms silver fluoride which is a soluble salt.

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13
Q

What are the names of the two acids produced when chlorine reacts with water?

A

Chloric acid and hydrogen chloride.

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14
Q

What is the reaction for chlorine reacting with cold, dilute sodium hydroxide?

A

Cl2 + 2NaOH –> 2NaCl + NaOCl + H2O

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15
Q

What is the name for NaOCl and what is its use?

A

Sodium chlorate

Household bleach

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16
Q

What is the reaction for chorine reacting with water?

A

Cl2 + H2O –> HCl + HClO

17
Q

Whats the reaction for chlorine reacting with water in sunlight?

A

2Cl2 + 2H2O –> HCl + O2

18
Q

How do NaF and NaCl react with H2SO4?

A

NaCl + H2SO4 –> NaHSO4 + HCl

NaF + H2SO4 –> NaHSO + NaF

19
Q

How does NaBr react with H2SO4?

A

NaBr + H2SO4 –> NaHSO4 + HBr

2HBr + H2SO4 –> Br2 + SO2 + 2H2O

20
Q

How does NaI react with H2SO4?

A

NaI + H2SO4 –> NaHSO4 + HI
2HI + H2SO4 –> I2 + SO2 + 2H2O
6HI + SO2 –> H2S + 3I2 + 2H2O