Reactions of metal ions in aqeous solution Flashcards
Iron (ii) with NaOH
[Fe(H2O)6}2+ + 2OH- –> Fe(H2O)4(OH)2 + 2H2O
Green ppt
Iron (ii) with XS NaOH
doesn’t happen
Iron (ii) with NH3
[Fe(h2O)6]2+ + 2NH3 –> Fe(H2O)4(OH)2 + 2NH4+
Green ppt
Iron (ii) with XS NH3
doesn’t happen
Iron (ii) with Na2CO3
[Fe(H2O)6]2+ + CO32- –> FeCO3 +6H2O
green ppt
Copper (ii) with NaOH
[Cu(H2O)6]2+ + 2OH- –> Cu(H2O)4(OH)2 + 2H2O
blue ppt
Copper (ii) with XS NaOH
doesn’t happen
Copper (ii) with NH3
[Cu(H2O)6]2+ +2NH3 –> Cu(H2O)4(OH)2 + 2NH4+
blue ppt
Copper (ii) with XS NH3
Cu(H2O)4(OH)2 + 4NH3 –> [Cu(H2O)2(NH3)4]2+ + 2H2O + 2OH-
deep blue solution
Copper (ii) with Na2CO3
[Cu(H2O)6]2+ + CO32- –> CuCO3 + 6H2O
blue/green ppt
Iron (iii) with NaOH
[Fe(H2O)6]3+ + 3OH- –> Fe(H2O)3(OH)3 + 3H2O
brown ppt
Iron (iii) with XS NaOH
doesn’t happen
Iron (iii) with NH3
[Fe(H2O)6]3+ + 3NH3 –> Fe(H2O)3(OH)3 + 3NH4+
brown ppt
Iron (iii) with XS NH3
doesn’t happen
Iron (iii) with Na2CO3
2[Fe(H2O)6]3+ + 3Co32- –> 2Fe(H2O)3(OH)3 + 3CO2 + 3H2O
brown ppt and CO2