solubility Flashcards
is lattice enthalpy always positive or always negative
always negative
define hydration enthalpy (deltaH hyd)
the enthalpy change when one mole of gaseous ions dissolves in water to form an infinitely dilute solution
define enthalpy of solution (deltaH soln)
the enthalpy change when 1 mole of an ionic solid is dissolved in water to form an infinitely dilute solution.
deltaH solution =
deltaH hydration - deltaH lattice
what causes the lattice enthalpy to be more exothermic
increased ionic charge
decreased ionic radius
what is lattice enthalpy a measure of
the strength of the ionic bond (Moree negative value means stronger ionic bond)
is hydration enthalpy always negative or always positive
always negative (exothermic process)