group 1 and 2 Flashcards

1
Q

why is group II more polarising than group I

A

they have a smaller radius and higher charge

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2
Q

why does group I form more stable carbonates

A

larger ionic radius and smaller charge

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3
Q

metal + oxygen

A

metal oxide

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4
Q

metal + chloride

A

metal chloride

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5
Q

metal + water

A

hydroxide + hydrogen

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6
Q

acid + base

A

salt + water

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7
Q

oxide + water

A

hydroxide

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8
Q

oxide + acid

A

salt + water

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9
Q

trend of solubility descending group II sulphates

A

less soluble

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10
Q

trend of solubility descending group II hydroxides

A

more soluble

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11
Q

what factors increase polarising ability

A

high charge
small size

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12
Q

trend of thermal stability descending group I and II

A

increases

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13
Q

why do group I form more stable carbonates

A

larger ionic radius
smaller charge

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14
Q

nitrate ion

A

NO3 -

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15
Q

carbonate ion

A

CO3 2-

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16
Q

why do carbonates become more stable descending a group

A

larger ionic radius

17
Q

why do carbonates decompose more readily with more polarising ions

A

higher charge
smaller radius

18
Q

decomposition of a group II carbonate to a group II oxide process

A

smaller cation is more polarising and distorts the electron cloud of the carbonate anion
CO2 is given off, leaving the oxide

19
Q

test for carbonate (of group I and II)

A

heat with blue flame
test gas given off with limewater
time how long limewater takes to go cloudy

20
Q

apparatus for carbonate I and II test

A

test tube (carbonate) ->heated w bunsen
bung
delivery tube
test tube (limewater)

21
Q

do group II nitrates decompose fully or partially

A

fully

22
Q

products of group II nitrates decomposing (fully)

A

oxide + nitrogen dioxide + oxygen

23
Q

do group I nitrates decompose fully or partially

A

partially

24
Q

products of group I decomposition (partially)

A

nitrate(III)salt + oxygen

25
Q

which group one nitrate decomposes fully (the exception)

A

lithium nitrate

26
Q

experiment to test nitrates (group I and II)

A

nitrate in a heating test tube
heat with blue flame
note change in appearance of solid, time taken and wether NO2/O2 involved

27
Q

colour of nitrogen dioxide gas

A

brown

28
Q

test for oxygen gas

A

relights a glowing splint

29
Q

identification of S block elements flame tests

A

clean nichrome wire by dipping in conc HCL and holding in blue bunsen flame
repeat until no colour is seen
dip rod in conc HCL then the solid
tip of wire in hottest part of bunsen flame and note the first colour

30
Q

flame colour lithium

A

red

31
Q

flame colour sodium

A

yellow/orange

32
Q

flame colour potassium

A

lilac

33
Q

flame colour rubidium

A

violet

34
Q

flame colour caesium

A

violet

35
Q

flame colour magnesium

A

colourless

36
Q

flame colour calcium

A

yellow-red

37
Q

flame colour strontium

A

red

38
Q

flame colour barium

A

pale green

39
Q

what causes the emission spectrum

A

electrons gain energy on heating and are promoted to a higher energy level shell
when returned to previous level they release the excess energy as light at a specific frequency