Shapes Of Molecules Flashcards

1
Q

What does the shape of a molecule depend on?

A

The charge clouds that are moving around a central nucleus

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

What is a charge cloud?

A

An area where you have a large chance of finding an electron

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Pairs/clouds of electrons repel eachother…

A

Until they are as far apart as possible in a 3D space

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

The electrons repelling each other until they are as far apart as possible does what?

A

Keeps repulsion at a minimum so that they are the most stable

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

What does a “stick” represent when drawing molecules?

A

Both atoms and the bond are in the same plane

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

What does a solid wedge mean when drawing a 3D molecule?

A

The bond is coming out towards us

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

What does the dotted/broken line represent when drawing a 3D molecule?

A

The bond is going into the paper- the bond is moving away from us

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

AB2?

A

B-A-B (as far apart as possible)
Linear
180 degrees
2 charge clouds

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

AB3?

A

3 charge clouds
120 degrees
Trigonal planar (flat triangle)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

AB4?

A

4 charge clouds
109.5 degrees
Tetrahedral shape

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

AB5?

A

5 charge clouds
Trigonal bipyramid
90 degrees
120 degrees

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

AB6?

A

6 electron clouds
Octahedral
90 degrees

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Examples: BeCl2?

A

Linear
180 degrees

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Examples: BF3?

A

Trigonal planer
120 degrees

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Examples: CH4?

A

Tetrahedral
109.5 degrees

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

PCl5?

A

120 degrees
90 degrees
Triganol bypyramid

17
Q

SF6?

A

90 degrees
Octahedral

18
Q

What are lone pairs of electrons?

A

Electrons in the outer shall that aren’t involved in bonding

19
Q

Do lone pairs of electrons repel the bonding pairs of electrons further apart or closer together?

A

Closer together

20
Q

For each lone pair, how much is the bond angle reduced by?

A

2.5 degrees for each lone pair

21
Q

Example: ammonia?

A

Four charge clouds
3 bonding pairs and one lone pair
107
Pyramidal

22
Q

Example: water?

A

4 charge clouds
2 bonding pairs and 2 lone pairs
104.5 degrees
Bent

23
Q

How to work out shapes?

A

1) figure out which group the central atom is in so then we can figure out the number of valence electrons
2) how many atoms are bonded to the central atom?
3) overall charge of the molecule?- if negative need to add electron, if positive need to remove electron
4) calculate the total number of electrons then divide by 2 to figure out how many electron pairs there are
5) compare to bonded atoms to check for lone pairs