Shapes Of Molecules Flashcards
What does the shape of a molecule depend on?
The charge clouds that are moving around a central nucleus
What is a charge cloud?
An area where you have a large chance of finding an electron
Pairs/clouds of electrons repel eachother…
Until they are as far apart as possible in a 3D space
The electrons repelling each other until they are as far apart as possible does what?
Keeps repulsion at a minimum so that they are the most stable
What does a “stick” represent when drawing molecules?
Both atoms and the bond are in the same plane
What does a solid wedge mean when drawing a 3D molecule?
The bond is coming out towards us
What does the dotted/broken line represent when drawing a 3D molecule?
The bond is going into the paper- the bond is moving away from us
AB2?
B-A-B (as far apart as possible)
Linear
180 degrees
2 charge clouds
AB3?
3 charge clouds
120 degrees
Trigonal planar (flat triangle)
AB4?
4 charge clouds
109.5 degrees
Tetrahedral shape
AB5?
5 charge clouds
Trigonal bipyramid
90 degrees
120 degrees
AB6?
6 electron clouds
Octahedral
90 degrees
Examples: BeCl2?
Linear
180 degrees
Examples: BF3?
Trigonal planer
120 degrees
Examples: CH4?
Tetrahedral
109.5 degrees
PCl5?
120 degrees
90 degrees
Triganol bypyramid
SF6?
90 degrees
Octahedral
What are lone pairs of electrons?
Electrons in the outer shall that aren’t involved in bonding
Do lone pairs of electrons repel the bonding pairs of electrons further apart or closer together?
Closer together
For each lone pair, how much is the bond angle reduced by?
2.5 degrees for each lone pair
Example: ammonia?
Four charge clouds
3 bonding pairs and one lone pair
107
Pyramidal
Example: water?
4 charge clouds
2 bonding pairs and 2 lone pairs
104.5 degrees
Bent
How to work out shapes?
1) figure out which group the central atom is in so then we can figure out the number of valence electrons
2) how many atoms are bonded to the central atom?
3) overall charge of the molecule?- if negative need to add electron, if positive need to remove electron
4) calculate the total number of electrons then divide by 2 to figure out how many electron pairs there are
5) compare to bonded atoms to check for lone pairs