Secondary Metabolites Flashcards
Takes place in most/all cell organisms. Products are part of normal anabolic and catabolic rxn.
Primary metabolism
Produces compounds other than primary compounds
Secondary metabolism
Organic compounds with no direct function in growth; not found in all plants
Secondary metabolites
Functions of secondary metabolites
Defense (vs. herbivores, microbe, allelopathic plants), attract insects, support
Major groups of secondary metabolites
Terpenes, phenolics, nitrogen containing compounds
Largest group of secondary products; insoluble
Terpenes
Example of terpenes
Essential oils, sterols, cartenoid pigment, plant hormones
Terpene responsible for odors and flavor lime citrus and mint; volatile; role - insect repellent
Essential oils
Include cartenoid pigments and rubber
Polyterpenes
Role of cartenoid pigments
Attraction
Sugars bonded to other sugars
Glycosides
Terpene glycosides with detergent properties
Saponin
3 forms of glycosides
Steroid glycosides, steroid alkaloid glycosides, triterpene glycosides
Terpene without sugars
Aglycones
Role of saponin
Defense against fungi
Natural source of hydrogen cyanide
Cyanogenic glycosides (ex: amygdalin in Rosaceae)
Role of cyanogenic glycosides
Toxic to herbivores (poisin- HCN - inhibits metalloprotein)
Example of cyanogenic glycosides
Cassava
Examples of terpenes
Menthol (cough), camphor (disinfectant), digitalin (cardiotonic), oleandrin (heart poison)
Derived from aromatic amino acids
Phenolics
Highly complex, second most abundant phenolic; component of cell walls, strengthen tissues
Lignin
Protective functions of lignin
Deter feeding, indigestible, blocks growth of pathogen
Provides color to attract insects (blue to red)
Anthocyanin
Protect from UV; form patterns/ nectar guide
Flavonols and flavones
Found in legumes; has phytoalexin antimicrobial compounds that limits pathogen
Isoflavones
Phenolic polymer; can inactivate herbivore digestive enzyme; feeding repellent; antifungal and antibacterial (heartwood)
Tannins
Biosynthesized from amino acids
Nitrogen containing compounds
Categories of nitrogen containing compounds
Alkaloid, no protein amino acid, plant protein
Known primarily for pharmacological properties
Alkaloids
Characteristics of alkaloids
Soluble, one nitrogen atom, high biological activity
Role of alkaloids
Defense against predators
Alkaloids in plants
Morphine (poppy, painkiller), codeine (poppy, cough), vincristine (chichirica, leukemia), nicotene (tobacco, stimulant), quinine (malaria)
For defense against herbivory, block protein synthesis, can be mistakenly incorporated in protein
Non protein amino acid
Chemically diverse group of secondary metabolites with strong antimicrobial activity
Phytoalexin
Phytoalexin can be found in
Isoflavonoids (legumes), sesquiterpenes (potato)