review

Question 1

kinetics vs thermodynamics

Answer 1

kinetics- how fast

thermo- spontanaity - will the rxn occur

Question 2

catalysts

Answer 2

alter kinetics, not thermo

• ater rate, not equilibrium
• will change K (hoe fast it takes to get to equ) but not Ksp (equ position stays the same)

Question 3

2 ways to get Keq?

Answer 3

1. lass of mass

2. from delts G: deltaG’= -RTlnKeq

Question 4

when delta G is not at standard conditions ( reactants at 1M, 1atm, 25 C)

Answer 4

delta G’ = deltaG + RT ln Q

Question 5

if ln (less than 1)

Answer 5

negative number

Question 6

E cell =

Answer 6

reduction pot + oxidation potencial

Question 7

how to find Ecell in non standard conditins

Answer 7

E cell = Ecell’ - 0.06/n log Q

Question 8

negative side of bettery

Answer 8

is the small lil line

Question 9

OH are usually insoluble except when bound with

Answer 9

group 1 and CaStrBa

Question 10

at pka

Answer 10

here (horizontal plateau where pH stays relativley constant) enough base has been added to neutralize 1/2 acid

at equivalence point (pH jumps alot) enough base to neutralize all acid - they are equal

Question 11

bond dissociation energy is

Answer 11

the energy to break bonds

• delta H = bond dis E for all reactants - bond dis E for all products