Recognising reagents - aliphatic Flashcards

1
Q

H2 / Ni

A
  • Alkene to alkane
  • Nitrile to amine
  • Hydroxynitrile to amine
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2
Q

NaCN(aq)/H+(aq)

A
  • Aldehyde to hydroxynitrile
  • Ketone to hydroxynitrile
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3
Q

H2O (g)/H3PO4

A

Alkene to alcohol

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4
Q

H3PO4 or H2SO4, heat

A

Alcohol to alkene

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5
Q

Hydrogen halide e.g. HBr

A

Alkene to haloalkane

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6
Q

NaCl/NaBr, H2SO4

A

Alcohol to haloalkane
(also produces NaHSO4 + H2O)

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7
Q

CN-/ethanol

A

Haloalkane to nitrile

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8
Q

NH3/ethanol

A

Haloalkane to amine

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9
Q

NaBH4

A
  • Ketone to alcohol
  • Aldehyde to alcohol
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10
Q

K2Cr2O7/ H2SO4, reflux

A
  • Alcohol to ketone
  • Aldehyde to carboxylic acid
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11
Q

K2Cr2O7/ H2SO4, distillation

A

Alcohol to aldehyde

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12
Q

NH3 (no ethanol)

A

Acyl chloride to primary amide

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13
Q

+ Primary amine

A

Acyl chloride to secondary amide

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14
Q

SOCl2

A

Carboxylic acid to acyl chloride

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15
Q

H2O

A

Acyl chloride to carboxylic acid

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16
Q

H2O/HCl, heat

A
  • Nitrile to carboxylic acid
  • Hydroxynitrile to carboxylic acid
17
Q

Alcohol, conc H2SO4

A
  • Carboxylic acid to ester
18
Q

Dilute acid, heat

A

Ester to carboxylic acid

19
Q

OH-, heat

A

Ester to carboxylate

20
Q

Alcohol

A

Acyl chloride to ester

21
Q

Carboxylic acid/H2SO4, OR acid anhydride

A

Alcohol to ester

22
Q

NaOH (aq)

A
  • Haloalkane to alcohol
  • Possibly ester to carboxylate
23
Q

Halogen, UV light

A

Alkene to haloalkane