Rates Of Reaction (4) Flashcards

1
Q

What are the 4 things that affect a rate of reaction

A

Temperature

Concentration (pressure for gases)

Catalyst

Size of particles / surface area

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2
Q

Rate of reaction equation:

A

Rate of reaction = Amount of reactant used OR amount of product formed / Time

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3
Q

What are the 3 ways to measure the speed of a reaction

A

Precipitation

Change in mass

The volume of gas given off

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4
Q

What is precipitation

A

When the product of the reaction is a precipitate which clouds over the solution

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5
Q

How to measure precipitation

A

Observe a marker and measure how long it takes to dissapear

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6
Q

How to measure change in mass

A

Do the reaction on a weight. The reaction has finished when the weight stops dropping. The quicker the weight drops, the quicker the reaction

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7
Q

When should you use the change in mass measurement

A

When a gas is produced

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8
Q

Which is the most accurate way to measure the rate of reaction

A

Change in mass

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9
Q

The third way - ‘the volume of gas given off’ involves the use of a gas ___________ to measure the volume of gas given off. The more gas given off during a time interval, the ___________ the reaction

A

Gas syringe

Faster

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10
Q

1 disadvantage of each method of measurement

Precipitation

Change in mass

Volume of gas given off

A

Precipitation: People may not degree when the marker disappears

Change in mass: Gas is released straight into the room

The volume of gas given off: If the reaction is too vigorous, you can easily blow the plunger out of the end of the syring

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11
Q

What does the reaction of hydrochloric acid and marble chips demonstrate the effect of

A

The effect of breaking the solid up into smaller bits

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12
Q

How to do the reaction of hydrochloric acid and marble chips

A

Fill a flask with hydrochloric acid and connect it to a delivery tube to another upside-down measuring cylinder in a trough of water. Drop marble chips in a solution of hydrochloric acid and start the timer immediately. The Co2 given off will create bubbles. You can measure the co2 given off by finding the difference between the water before and after Do the same experiment again with the same mass of marble chips but crush them up more, or change the temperature. See the difference.

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13
Q

Good experiment to show the effect of catalysts

A

The decomposition of hydrogen peroxide

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14
Q

How to do the decomposition of hydrogen peroxide to prove the effect of catalysts.

A

Hydrogen peroxide decomposes to form heavy water and oxygen. This is normally a slow reaction but manganese oxide speeds it up

Since oxygen is the gas given off you can just use a syringe to measure it

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15
Q

What does a rate of reaction graph look like

A

This

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16
Q

What is collision theory

A

The theory that a rate of reaction simply depends on how often and how hard the reacting particles collide with each other.

17
Q

How does higher temperature effect the rate of reaction

A

When temperature is increased, particles have more energy and move quicker meaning that they will collide more frequently.

18
Q

How does concentration effect the rate of reaction

A

If a solution is made more concentrated it means there are more particles of reactant around. Which makes collisions more likely.

19
Q

How does pressure effect the rate of reaction

A

In a gas, increasing the pressure means the particles are more squashed together together (compact) so they are going to collide more frequently.

20
Q

How does larger surface area effect the rate of reaction

A

If the surface area is increased then the particles around it that want to react have more area to react with, hence, more succesful collisions.

21
Q

How does a catalyst effect the rate of reaction

A

A catalyst works by giving the reacting particles a surface to stick to which increases the number of succesful collisions by lowering the activation energy

22
Q

The initial energy is known as the _______________ energy and it’s needed to break the initial bonds

A

Activation energy

23
Q

Energy must be supplied to break existing bonds - so bond breaking is an ______________ process

A

Endothermic

24
Q

Energy is released when new bonds are formes - so bond formation is an __________________ process

A

Exothermic

25
Q

In an endothermic reaction, energy is _________ ______

A

Taken in

26
Q

In an exothermic reaction, energy is ________ ______

A

Given out

27
Q

An endothermic reaction is one which _________ _____ energy from the surroundings, usually in the form of heat and shown by a ________ in temperature

A

Takes in energy

Fall

28
Q

An exothermic reaction is one which _________ _____ energy from the surroundings, usually in the form of heat and usually shown by a ________ in temperature

A

Gives out

Rise

29
Q

The overall change in energy in a reaction is called the ______________ change. It has the symbol ______

A

Enthalpy. ΔH

30
Q

Units of ΔH

A

KJ/mol

31
Q

If the reaction is exothermic, the value is _____________ because the reaction is _________ _____ energy

A

Negative

Giving out

32
Q

If the reaction is endothermic, the value is ____________ because the reaction is _________ _____ energy

A

Positive

Taking in