Enthalpy (4) Flashcards
What does calorimetry allow you to do
Measure the amount of energy transferred in a chemical reaction
What are the different types of calorimetry
Dissolving, Displacement, Neutralisation
And Combustion
How do you measure the energy transferred in enthalpy reactions
Measure the temperatures at the beginning. Mix them together and measure the temperature of the solution at the end of the reaction (after)
How can you lose less heat to the surroundings
Put the polystyrene cup into a beaker of cotton wool to give more insulation + put a lid on the cup
You can lose less heat to the surroundings by putting the polystyrene cup into a beaker of cotton wool to give more _____________ + put a lid on the cup to reduce energy lost by ________________
Insulation
Evaporation
Example of enthalpy reaction
Put 25cm3 of hydrochloric acid in a polystyrene cup and record the temperature of the acid.
Put 25cm3 of dilute sodium solution in a measuring cylinder and record its temperature.
Mix.
Take the temperature every 30 seconds and record the highest temperature it reaches
To measure the amount of energy produced when a fuel is burnt, simply burn the fuel and use the flame to heat up some _________. This is _______________ calorimetry
Water
Combustion
Combustion calorimetry uses a metal container, usually made of __________ because it conducts heat so well
Copper
What is important to remember when heating up the water
To reduce draughts. Use a screen to act as a draught excluder
Calorimetry - Combustion:
Put 50g of water in the copper can and record its temperature.
_________ the spirit burner and lid.
Put the spirit burner underneath the can and burn the wick. Heat the water stirring constantly until the temperature reaches about _____.
Put out the flame using the burner lid and measure the final temperature of the _________.
_________ the spirit burner and lid again
You can then use the temperature measurements you’ve taken to calculate the __________ change
Weigh 50° Water Weigh Enthalpy
How to calculate the heat heat energy transferred
Measure how much fuel you’ve burnt
Measure the temperature change of the water
You can now work out how much energy is supplied by each gram of fuel
The specific heat capacity of water is ________ what does this mean.
4.2J/g/°C
So it takes 4.2 joules of energy to raise the temperature of 1g of water by 1°C