Page 24 Flashcards
How does the number of R groups on the carbon with the leaving group affect E2 reactions?
A: Increasing the number of R groups forms more highly substituted, stable alkenes, making the reaction faster.
Why do tertiary alkyl halides react faster in E2 mechanisms compared to primary alkyl halides?
A: Tertiary alkyl halides form more substituted (and more stable) alkenes during the reaction, lowering the activation energy.
Why do tertiary alkyl halides react faster in E2 mechanisms compared to primary alkyl halides?
A: Tertiary alkyl halides form more substituted (and more stable) alkenes during the reaction, lowering the activation energy.
In E2 reactions, which product is more stable: a monosubstituted alkene or a disubstituted alkene?
A: The disubstituted alkene is more stable because it has greater substitution around the double bond, increasing stability through hyperconjugation and inductive effects.
What happens in the elimination reaction of 1-bromobutane?
A: A primary alkyl halide (1-bromobutane) forms a monosubstituted alkene, which is less stable.
What happens in the elimination reaction of 2-bromo-2-methylpropane?
A: A tertiary alkyl halide (2-bromo-2-methylpropane) forms a disubstituted alkene, which is more stable.