Page 17 Flashcards

1
Q

What is represented by the peak of the energy diagram in an E2 reaction?

A

A: The transition state, where bonds are partially broken and formed.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

In the transition state of an E2 reaction, which bonds are partially broken?

A

A: The C-H and C-Br bonds are partially broken.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Which bonds are partially formed in the E2 reaction transition state?

A

A: The O-H bond (with the base) and the π bond of the alkene are partially formed.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

What does E_a represent on the energy diagram?

A

A: E_a represents the activation energy required for the reaction to proceed.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

How does the leaving group behave in the transition state of an E2 reaction?

A

A: The leaving group bears a partial negative charge as it departs.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Why is the E2 reaction considered a concerted mechanism?

A

A: Because all bond-breaking and bond-forming processes occur in a single step without intermediates.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

What is the energy difference between reactants and products on the diagram?

A

A: It represents the overall energy change ( \Delta H ) of the reaction.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

What role does the base play in the transition state of an E2 reaction?

A

A: The base abstracts the proton from the β-carbon, forming a partial O-H bond.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Why is the transition state the highest point on the energy diagram?

A

A: It represents the point of maximum energy where old bonds are weakened, and new bonds are partially formed.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

What products are formed at the end of the E2 reaction shown in the diagram?

A

A: An alkene (CH₂=CH₂), H₂O, and the leaving group (Br⁻).

How well did you know this?
1
Not at all
2
3
4
5
Perfectly