Oxidation Number Rules Flashcards

1
Q

Free (uncombined) elements

A

Free (uncombined) elements have an oxidation number of zero

This includes polyatomic elements

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2
Q

Monatomic ions

A

Monatomic ions:
Oxidation number = charge of ion

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3
Q

Oxygen

A

Oxygen:

Usually -2

Exceptions:
Hydrogen peroxide: H2O2 (-1)
Peroxide ion: O22- (-1)

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4
Q

Hydrogen

A

Hydrogen:

Oxidation = +1

Except when bound to metals in binary compounds (-1)

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5
Q

Group 1A

A

Group 1A:

+1

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6
Q

Group 2A

A

Group 2A:

+2

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7
Q

Al (Group 3A)

A

Al (Group 3A):

+3

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8
Q

F (Group 7A)

A

F (Group 7A):

-1

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9
Q

Molecular formula or formula unit

A

Molecular formula or formula unit:

Oxidation number sum must equal zero

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10
Q

Polyatomic ions

A

Polyatomic ions:

Sum of oxidation numbers must = ion charge

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11
Q

Oxidation numbers

A

Can be integers or fractions

E.g. one O in O2- = -1/2

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