Chapter 03B: Molecules, Compounds, and Chemical Equations Flashcards
Molecular mass
Sum of atomic masses (in amu) in a molecule.
Formula mass
Sum of the atomic masses (in amu) in a formula unit of an ionic compound
Remember:
formula unit : molecular formula
as
ionic compound : molecular compound
Mass percent composition
Mass percent of each element in a compound
mass % = (__n) (molar mass of element) x 100
(molar mass of compound)
Where n = mol of element in compound
E.g. CO2, n = 2 when calculating mass % of O
Calculating empirical formulas
1) % percent –> g –> mol (for each element)
2) Set up unsimplified ratio (framework of empirical formula)
Simplify: divide by the smallest # of mol
3) Change simplified mole ratios to integer subscripts
*If element(s) in ratio are not close to a whole number, multiply the ratio, then round –> empirical formula
Combustion analysis
Technique for analyzing compounds, mostly for organic compounds
Uses product mass, reactant composition to determine empirical formula (and eventually molecular formula)
Calculating molecular formula from empirical formula
Molecular formula is a multiple of empirical formula
Molecular formula = (empirical formula)n
Where n = positive integer
n = molar mass
empirical formula molar mass
Chemical reaction
Chemical change; 1+ substances are changed into 1+ new substances
Chemical equation
Shorthand notion for chemical reactions
Used for:
- displaying reactants & products
- indicating specific amounts of materials used/produced
Organic compounds
Mainly made of C and H
Sometimes with O, N, P, S (+ trace amounts of other elements)
C in organic compounds (3 details)
1) C bonds almost always covalently
2) Each [starter] C forms 4 bonds somehow:
*4 single, 2 double, 1 triple + 1 single, etc.
*e.g. C2H2 and CH3COOH
3) C can form limitless changes of C atoms (unique)
*straight, branched, and ring-form
Organic compounds –> two subcategories (nomenclature)
Organic compounds
Hydrocarbons Functionalized hydrocarbons
Hydrocarbons
Organic compounds with ONLY C and H
E.g. common fuels
Alkanes
Hydrocarbons with only single bonds
Alkenes
Hydrocarbons with double bonds
Alkynes
Hydrocarbons with triple bonds