monosaccharides and disaccharides Flashcards
two molecules that are made of the same atoms connected in the same sequence, but the atoms are positioned differently in space
stereoisomers
non-superimposable mirror images
enantiomers
D-Ribose and L-Ribose are
enantiomers
stereoisomers that are not enantiomers (not mirror images)
diastereomers
D-arabinose and D-ribose are
diastereomers
diastereomers that differ at a single chiral carbon
epimers
D-glucose and D-mannose are ____that differ at____
epimers
second carbon position
an aldehyde and an alcohol make a
hemiacetal
a ketone and an alcohol make a
hemiketal
the two possible diastereomers that are formed because of cyclization
anomers
alpha D glucose OH group is
not in the same plane as the oxygen
beta D glucose OH group is
in the same plane as the oxygen
monosaccharides may readily undergo several oxidation reactions in the presence of metal ions or certain enzymes
oxidation
D-gluconic acid is an example of
aldonic acid
D-glucuronic acid is an example of
uronic acid
D-glucaric acid is an example of
aldaric acid
can be produced if the carbonyl groups of aldonic and uronic acids react with an OH group in the same molecule
lactone
example of naturally produced lacone
L-ascorbic acid (vitamin C)
powerful reducing agent that protects cells from reactive oxygen and nitrogen species
Vitamin C
another name for sugar alcohols
alditols
sugar alcohols are produced by the _____of aldehyde and ketone groups of monosaccharides
reduction
free OH groups of carbohydrates can be converted to esters by reaction with acids
esterfication