Module 7 - 1 Flashcards

1
Q

What are the physiological functions of carbohydrates?

A

Sources of energy, energy storage, structural roles, cellular interaction, cellular identification, information transfer, and signaling.

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2
Q

What are the two major classes of carbohydrates?

A

Aldoses and ketoses.

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3
Q

What is the empirical formula of carbohydrates?

A

(CH2O)n, where n ≥3 (usually 3-6).

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4
Q

What are chiral carbons?

A

Asymmetric carbons in monosaccharides.

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5
Q

How is the designation of a sugar as either D or L determined?

A

Based on the configuration of the chiral carbon most distant from the carbonyl oxygen.

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6
Q

What is the reference molecule for determining D or L designation?

A

D-glyceraldehyde.

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7
Q

How many stereoisomers are present in a molecule with n chiral centers?

A

2^n stereoisomers.

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8
Q

What are epimers?

A

Sugars that differ at a single chiral center.

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9
Q

What are cyclic structures in carbohydrates?

A

Cyclized structures of longer carbohydrates in solution.

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10
Q

What are the two types of cyclic structures?

A

Pyran and furan ring structures.

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11
Q

What is the result of the reaction of an internal alcohol with an aldehyde?

A

Hemiacetal formation.

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12
Q

What is the result of the reaction of an internal alcohol with a ketone?

A

Hemiketal formation.

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13
Q

What are the monosaccharide families?

A

Aldoses and ketoses.

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14
Q

What are the physiological roles of carbohydrates?

A

Sources of energy, energy storage, structural roles, cellular interaction, cellular identification, information transfer, and signaling.

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15
Q

What is the designation of D or L relative to?

A

The reference molecule D-glyceraldehyde.

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16
Q

What is the maximum number of stereoisomers in a molecule with 4 chiral centers?

A

16 stereoisomers.

17
Q

What is the maximum number of stereoisomers in a molecule with 3 chiral centers?

A

8 stereoisomers.

18
Q

What are the categories of isomers within carbohydrates?

A

Epimers and others.

19
Q

What are the common sugars?

A

They must be memorized.

20
Q

What are the two types of hemiacetals?

A

Aldoses and ketoses.

21
Q

What are the two types of hemiketals?

A

Aldoses and ketoses.

22
Q

What is a pyranose?

A

Six-membered sugar ring

23
Q

What is a furanose?

A

Five-membered sugar ring

24
Q

What is the process of cyclization of glucose?

A

Involves C5 hydroxyl and C1 aldehyde

25
Q

What is an anomeric carbon?

A

Carbon that becomes chiral after cyclization

26
Q

What are the two stereoisomers produced during cyclization of glucose?

A

Alpha and beta forms

27
Q

What is the relationship between alpha and beta forms?

A

They are anomers of each other