Measuring Reaction Rates Flashcards
Average rate
rate when ∆t is clearly measurable
What are the two factors that affect reaction rates?
changes to collision frequency/activation energy, changing A (surface area/changing phases)
Catalysts
substance that increases the rate of a chemical reaction by providing an alternative pathway but is not consumed by the reaction
Instantaneous rate
rate of reaction at any specific time
Initial rate
instantaneous rate when the reaction starts
Rate laws/rate equation
mathematical expressions that relate the rate of a chemical reaction to the concentrations of reactants
Order of a reaction
the power to which a concentration must be raised to correctly calculate the rate
Overall reaction order
sum of all individual orders
k units for zeroth order reactions
M/s
k units for first order reactions
1/s
k units for second order reactions
1/Ms
k units for third order reactions
1/M^2s
Method of initial rates
select 2 sets of rate data where all concentrations but one are the same and set up a ratio of the 2 rates and the 2 rate laws