ES 3 Flashcards

1
Q

What is electrolysis?

A

decomposing a compound using an electric current

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2
Q

What happens at the electrodes?

A

Electrons are lost or gained by ions

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3
Q

Which is the negative electrode?

A

Cathode

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4
Q

What are usually the products at the electrodes?

A

Cathode - metal
Anode - non-metal or hydrogen

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5
Q

Where do cations and anions migrate to?

A

Cations -> cathode
Anions -> anode

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6
Q

Why is it easier to carry out electrolysis do solution in aqueous state?

A

The ions become free to move

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7
Q

What happens at the anode ?

A

Oxidation

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8
Q

What happens to halide ions at the anode?

A

HAlogen is produced at the anode as they are oxidized more easily than water
2Cl- -> Cl2 + 2e-

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9
Q

What happens to sulfates and nitrates at the anode?

A

Oxidized less easily than water so oxygen gas is produced at the anode
2H2O -> O2 + 4H+ + 4e-

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10
Q

What happens to when the anode and metal solution are the same?

A

Metal anode loses mass as metal atoms change to ions and go into the solution

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11
Q

What is produced when a group 1 or 2 metal is aluminium, is at the cathode?

A

Hydrogen
2H2O(l) + 2e- -> 2OH-(aq) + H2(g)

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12
Q

What happens at the cathode if the solution is an acid?

A

Hydrogen is produced
2H+ (aq) + 2e- -> H2 (g)

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13
Q

What happens if a less reactive metal (not group 1 or 2) is at the cathode?

A

Metal atoms are formed
Metal ion (aq) + electrons -> metal atom (s)

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