ES 3 Flashcards
What is electrolysis?
decomposing a compound using an electric current
What happens at the electrodes?
Electrons are lost or gained by ions
Which is the negative electrode?
Cathode
What are usually the products at the electrodes?
Cathode - metal
Anode - non-metal or hydrogen
Where do cations and anions migrate to?
Cations -> cathode
Anions -> anode
Why is it easier to carry out electrolysis do solution in aqueous state?
The ions become free to move
What happens at the anode ?
Oxidation
What happens to halide ions at the anode?
HAlogen is produced at the anode as they are oxidized more easily than water
2Cl- -> Cl2 + 2e-
What happens to sulfates and nitrates at the anode?
Oxidized less easily than water so oxygen gas is produced at the anode
2H2O -> O2 + 4H+ + 4e-
What happens to when the anode and metal solution are the same?
Metal anode loses mass as metal atoms change to ions and go into the solution
What is produced when a group 1 or 2 metal is aluminium, is at the cathode?
Hydrogen
2H2O(l) + 2e- -> 2OH-(aq) + H2(g)
What happens at the cathode if the solution is an acid?
Hydrogen is produced
2H+ (aq) + 2e- -> H2 (g)
What happens if a less reactive metal (not group 1 or 2) is at the cathode?
Metal atoms are formed
Metal ion (aq) + electrons -> metal atom (s)