Earth Mat Flashcards - Ch 15
Metamorphism refers to predominantly solid state mineral and/or textural changes to a pre-existing “ parent ” rock, or
protolith
results from increasing temperature and/or pressure conditions over time
Prograde metamorphism
Devolatilization processes are particularly important in convergent margins where the loss of volatiles results in:
loss of highly mobile volatile components
Enhanced melting by an influx of volatiles
generation of high temperature anhydrous minerals
results from decreasing temperature and/or pressure so that lower temperature/pressure mineral assem blages develop that overprint earlier peak temperature/pressure mineral assemblages.
Retrograde metamorphism
serve as catalysts in retrograde metamorphism
Volatile components
involves the use of mineral assemblages or deformation characteristics of specific minerals to infer peak temperature and/or pressure conditions of metamorphism.
Geothermobarometry
A mineral assemblage of a metamorphic rock stable at current PTt is represented by an equilibrium assemblage
equilibrium assemblage
The onset of metamorphism begins at
~150–200°C.
a set of sedimentary processes that occur at temperatures less than ~ 150 – 200 ° C and at relatively low pressures (< 3 kbar or 10 km depth).
Diagenesis
occurs when the bulk composition of rocks changes as a result of chemical reactions with hot fluids of variable origin
Hydrothermal alteration
Volatile sources consist of:
“ Juvenile ” fluids derived from magma,
Seawater, which infi ltrates fractures and pore spaces
Fluids derived by devolatilization reactions, releases
H2O from amphibole, mica and serpentine minerals.
CO2 from limestone and dolostone
Meteoritic fluids
Connate fluids
High temperature alteration resulting in Na enrichment
Albitic
Albite, paragonite (Na - rich mica)
Occurs in hot spring environments and gold and copper porphyry deposits by the oxidation of sulfide minerals
Alunitic
Alunite and sulfate minerals
Low temperature decomposition of feldspars in acidic (low pH) conditions; occurs in gold deposits hosted by sedimentary rocks; clays
Argillic
Kaolinite, smectite, illite
Replacement by carbonate minerals at variable temperatures
Carbonatization
Decomposition of silicic rocks; associated with porphyry copper deposits
Phyllic
Sericite, quartz, pyrite
High temperature alteration of silicic magma resulting in K enrichment; commonly underlies phyllic zones
Potassic
Biotite, K - feldspar, adularia
Low to moderate temperature decomposition of basic and ultrabasic rocks enriched in pyroxene, amphibole, biotite and plagioclase; also occurs in gold and copper porphyry deposits
Propylitic
Chlorite, epidote, actinolite, tremolite
Alteration of feldspars
Sericitic
Sericite (fine - grained, white mica)
Low temperature alteration of basic and ultrabasic rocks
Serpentinization
Serpentine, talc
Replacement by silica minerals at variable temperatures
Silicification
Quartz, chert
Low temperature alteration of Ca - plagioclase to albite
Spilitization
Albite
Low temperature replacement of glass in volcanic rocks
Zeolite
Zeolite minerals
reactions involve reactions in which igneous rocks are “stewing in their own juices.”
Hot, vapor-rich fluids are commonly associated with igneous intrusions that provide the heat, fluid, and corrosive compounds to chemically alter minerals.
Deuteric
involves changes in solid rock composition resulting from hydrothermal fluids exchanging constituents with an outside source
Metasomatism
Uniform (isotropic) stress
tend to produce metamorphic rocks with:
Equant grains
Non foliated textures
Non - uniform stress is not equal in all directions and tends to produce metamorphic rocks containing
Inequant grains
Foliated textures
such protoliths include aluminum - rich rocks such as shale, mudstone and altered volcanic tuff (bentonite).
Pelite
The aluminous polymorph minerals kyanite, andalusite and sillimanite are useful temperature and pressure indicators –_________ – based on their respective mineral stability field
geothermobarometers
commonly develop from mud stone protoliths.
slates, phyllites and mica schists
Contact metamorphism of pelitic protoliths produces
non - foliated Hornfels
commonly occurs with andalusite in low pressure assemblages
Cordierite
____________ protoliths include quartz sandstone, arkosic sandstone and intermediate to silicic igneous rocks such as granite, granodiorite and their volcanic, equivalents.
Quartzofeldspathic or psammitic