Earth Mat Flashcards - Ch 1-6
Volume Mass of the layers of the Earth
Crust - <1% volume
Mantle - 83% volume, 68% Mass
Core - 16% volume, 32% mass
Depth of each layer of the earth
Litho- crust to upper mantle
Astheno- 100km to 660km
Mesosphere- 660-2900
Outer core- 2900-5150
inner core- 5150-6370
age and location of oldest oceanic crust
less than 180 mya, N. Atlantic and W. Pacific
Age of oldest continental crust
4.03 ga at NW territories Canada
Greenland and Australia greenstone belts -4.28 ga
Features of divergent boundaries
Continental rifts
Oceanic ridge system
Features of Convergent Boundaries
Subduction zones
Continental Collisions
Feature of Left stepping sinistral fault and right stepping sinistral fault
Pull-apart basin
Orogen
Examples of Hotspots
oceanic - Hawaii
Continental - Yellowstone
Divergent - Iceland
mass of subatomic particles
proton - 1.00728 amu
neutron - 1.00867 amu
Electron - 0.0000054 amu
Names of Hydrogen Isotopes
Hydrogen 1 - Hydrogen (protium)
Hydrogen 2 - Deuterium
Hydrogen 3 - Tritium
Properties of an electron
Principal Quantum no. or shell
Azimuthal Quantum no. or subshell
Magnetic Quantum no.
Spin no.
Energy required to remove an electron from its electron cloud
Ionization energy
elements that have low required 1st ionization energy
Electropositive elements
who introduced the concept of Electronegativity
Linus Pauling 1929
a uniaxial positive indicatrix has a shape of?
Prolate spheroid
what is electrical Neutrality
concept wherein amount of elements in a molecule must be equal to be stable with respect to their charges/electron configuration
what are the attractive and repulsive forces between ions of opposite charges
Coulomb attraction
Born Repulsion
Types of chemical bonds in Minerals
Ionic
covalent
metallic
van der waals
hydrogen bond
what bond is present with electronegativity difference of more than 1.68?
Ionic
covalent if less than 1.68
what are Pauling’s Rules
rules in cation-anion relationships in ionic bonds
1. Radius sum determines polyhedron formed by anions for each cation
2. Electrostatic valency rule - ionic is stable if sum of strength of bonds equals the charge of anions and cations themselves
3. Shared edges in polyhedra decreases stability, same charge and components share corners instead
4.High valency charge cations and Small coordination numbers dont share polyhedron elements
5. Rule of Parsimony- no. of diff cations and anions in a crydtal structure are small
Coordination number vs Coordination Polyhedron
CN - no. of nearest ions or atoms
CP - cluster of atoms bonded to coordination atoms
Trends in Radius Ratio:
Rcation/Ranion
<0.155 CN =2, Linear
0.155-0.225 CN =3, Triangular
0.225-0.414 CN =4, Tetrahedral
0.414-0.732 CN =6, Octahedral
0.732-1 CN =8, Cubic
>1 CN =12, Cubic, Hexagonal closest packed
when is substition of ions available?
if atomic radii difference are within 10-15%, limited if it exceeds and negligible if greater than 30%
describe substition in one coordination site compared to multiple
one coordination site - limited with ions of the same charge to maintain stability.
multiple - ions lf different charge are permitted so long as another coordination site is there to neutralize
exists when ions of same radii and charge substitute in a coordination site
Simple complete substitution
includes complete solid solution, were components (end members) can substitute in any proportion
what is Coupled ionic substitution
type of substitution where ions of diff charges in 2 different structural sites preserves the neutrality kf the crystal lattice
caused by different size limit of ions existing in its end components
Limited Ionic substitution
solid solution proportions that do not exist in nature due to atomic radii diff of components, could also exhibit exsolution
Miscibility gaps
what is a phase and a phase stability diagram
phase- mechanically seperable part of a system
diagram - disblay stable fields
compare eutectic and peritectic point
Eutectic- Condition where melt is in equilibrium w/ 2 diff solids
Peritectic - reaction occurs between a pre-existing solid phase and melt to produce a new solid phase
Compare invariant and incongruent melting
Invariant - occurs when rocks of different origin material melts into one material of same composition (opposite of eutectic)
Incongruent Melting - when a solid mineral phase melts to produce a melt and a different mineral with a different composition from the initial mineral
Compare continous and discontinous melting
continous - crystals and melt react to continously and incrementally change the composition of both, rewuires a solid solution
discontinous - crystals and melt react to produce a completely diff mineral negligible solid solution exists between the minerals
what does the solvus designate?
phase boundary line that seperares conditions in which complete solid solution occurs within a mineral series from conditions under which solid solution is limited
rule that governs the no. of phases that can coexist in equilibrium in any system
Gibbs Phase Rule
Phase = Components +2 - Freedom
where are stishovite and coesite usually found?
impact metamorphism, bomb sites, deep mantle
where are stishovite and coesite usually found?
impact metamorphism, bomb sites, deep mantle
Points and trends of the Silica phase diagram
Low Qtz - max 1200c at 3 gpa Hexagonal
High qtz - 500c to 1800c at 4gPa hexagonal
tridymite - 900c to 1400c less than 1 gpa Monoclinic
cristobalite -1400c to 1600c less than 1 gPa Tetragonal
coesite - From 2 GPa Monoclinic
stishovite - From 7.5 GPa Tetragonal
trends and points of Plagioclase 2 component phase diagram
NaAlSi4O8 Albite melting - 1118c
CaAlSi4O8 Anorthite - 1513c
trends and points in Anorthite- Diopside diagram, 2component nk solid solution phase diagram
CaAlSi4O8 Anorthite
CaMgSi2O6 Clinopyroxene Diopside
Anorthite liquidus - 1553c
Diopside Liquidus - 1392 c
Solidus - 1274c
trends and points of Albite and Orthoclase
perthite antiperthitr cut off - 40% orthoclase
>40 perthite then vice versa
comllete solid solution at 670c
Nepheline - Silica
NaSiO4 Nepheline
SiO2 Silica
67% cutoff of saturation for silica anything less is undersaturated then vice versa is over saturated
1070c melt of nepheline
1060c in silica
nepheline reacts with silica through discontinous melting to form albite
Trends and points of Forsterite-enstatite-Silica
MgSiO4 Forsterite
MgSi2O6 Enstatite
SiO2 Silica
Peritectic - 1585c
Eutectic - 1540c
Forsterite - 1880c liquidus
line of peritectic is at 30% silica
what are the percentages of abundance of oxygen and carbon isotopes?
O16 -99.7
O18 -0.2
O17- rare
C12 98.9
C13 1.1
C14 Radioactive
what is smow and what specimen was used for its basis?
Standard mean ocean water - describes the standard of O18/O16 ratios based from a belemnite of Pee Dee Formation of the Cretaceous perios due to the period being unusually warm
why are high O18/O16 ratios could mean glacial periods?
High ratios in ocean water could mean high rates of evaporation where vapor accumulated in the form of snow in glaciers.
These are trapped methane in underwayer environments that accumulated to the surface and caused the Paleocene-Eocene thermal maximum
Clathrates
percentage of ions that K40 decays into?
91% becomes Ca 40
9% becomes Ar40
fill in the appropriate isotope that the parent isotope decays into:
U238 -
U235 -
Th234 -
U238 - Pb206
U235 - Pb207
Th234 - Pb206
types of symmetry operations and their corressponding letter in expressions
Translation (t)
Rotation (n)
Reflection (m) enantiomorphic operations - changes handedness
Inversion (i or c)
Glide Reflection (g)
Rotoinversion (nbar)
screw inversion (n subscript a)
smallest unit of pattern that generate long range pattern seen in crystals
Motif