Developing Metals 1: Introduction Flashcards
When can transition metals be found on the periodic table
D block
What similarities do the elements in the first row of d block have
- all have outer electrons in the 4s subshell
- all have electrons filling the “inner” 3d subshell
What is the rule for 4s and 3d subshells
4s fills before 3d
Give electron of Scandium ( Sc) in terms of subshell ( all other elements in first row for similar pattern however are a few exceptions)
[1s2 2s2 2p6 3s2 3p6] 4s2 3d1
= [ Ar ] 4s2 3d1
- Ti = [Ar] 4s2 3d2
Which elements are expeptions in the trend of electron configuration of the first row of transition metals and why
Chronium and Copper = only contain 1 electron in the 4s subshell
Cr = [ Ar] 4s1 3d5
Cu = [Ar] = 4s1 3d10
Why do the first row of transition metals have similar properties and what do they difere by
- all have essentially the same outer electron arrangements
- differ by the addition of one or more electron to the inner 3d subshell ( not by number of complete electron shells)
What is the rule about how electrons are lost when transition metals form (+ve) ions
4s electrons are lost 1st the 3d
What is a typical characteristic of a transition metal ( in terms of ions)
Variable oxidation state
Eg. Iron can form Fe2+ or Fe3+
Definition of a transition metal
Element that can form one or more stable ions with an incomplete d subshell
Name 3 Common first row d block element ions that you may come across that aren’t actually transition metals
Explain why they are not
Sc 3+ =[Ar] - no d subshell
Zn2+ = [Ar] 3d10 - complete d subshell
Explain why copper is considered a transition metal despite Cu+ = [Ar] 3d10
Copper has another ion which coincides with the definition of a transition metal unlike Cu+
Cu2+ = [Ar] 3d9
What 4 general properties of transition elements are incomplete d subshells responsible for
- ) variable oxidation states
- ) catalytic action
- ) coloured compounds
- ) formation of complexes
Recap AS shapes of molecules and catalysis
Go to AS Deck
- Elements of Life : shapes of molecules
- Developing Fuels: Catalysts
- Ozone : Radiation & Radicals