Developing Metals 1: Introduction Flashcards

1
Q

When can transition metals be found on the periodic table

A

D block

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2
Q

What similarities do the elements in the first row of d block have

A
  • all have outer electrons in the 4s subshell

- all have electrons filling the “inner” 3d subshell

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3
Q

What is the rule for 4s and 3d subshells

A

4s fills before 3d

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4
Q

Give electron of Scandium ( Sc) in terms of subshell ( all other elements in first row for similar pattern however are a few exceptions)

A

[1s2 2s2 2p6 3s2 3p6] 4s2 3d1

= [ Ar ] 4s2 3d1

  • Ti = [Ar] 4s2 3d2
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5
Q

Which elements are expeptions in the trend of electron configuration of the first row of transition metals and why

A

Chronium and Copper = only contain 1 electron in the 4s subshell

Cr = [ Ar] 4s1 3d5

Cu = [Ar] = 4s1 3d10

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6
Q

Why do the first row of transition metals have similar properties and what do they difere by

A
  • all have essentially the same outer electron arrangements

- differ by the addition of one or more electron to the inner 3d subshell ( not by number of complete electron shells)

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7
Q

What is the rule about how electrons are lost when transition metals form (+ve) ions

A

4s electrons are lost 1st the 3d

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8
Q

What is a typical characteristic of a transition metal ( in terms of ions)

A

Variable oxidation state

Eg. Iron can form Fe2+ or Fe3+

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9
Q

Definition of a transition metal

A

Element that can form one or more stable ions with an incomplete d subshell

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10
Q

Name 3 Common first row d block element ions that you may come across that aren’t actually transition metals

Explain why they are not

A

Sc 3+ =[Ar] - no d subshell

Zn2+ = [Ar] 3d10 - complete d subshell

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11
Q

Explain why copper is considered a transition metal despite Cu+ = [Ar] 3d10

A

Copper has another ion which coincides with the definition of a transition metal unlike Cu+

Cu2+ = [Ar] 3d9

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12
Q

What 4 general properties of transition elements are incomplete d subshells responsible for

A
  1. ) variable oxidation states
  2. ) catalytic action
  3. ) coloured compounds
  4. ) formation of complexes
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13
Q

Recap AS shapes of molecules and catalysis

A

Go to AS Deck

  • Elements of Life : shapes of molecules
  • Developing Fuels: Catalysts
  • Ozone : Radiation & Radicals
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