D and F block elements Flashcards

1
Q

3d series is from

A

SC to zn

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2
Q

4 d series is from

A

Y to Cd

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3
Q

5 d series is from

A

La and Hf to Hg

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4
Q

6 d series is from

A

Ac and elements from Rf to Cn

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5
Q

The element which does not have electrons in s orbital during ground state

A

Pd

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6
Q

Which orbital protrude to the periphery very much and hence are more influenced by surroundings

A

D orbital

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7
Q

Ions of d^ n configuration show similarity in

A

Magnetic and electronic properties

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8
Q

In any row of d block elements the melting points of these metals rise to a maximum at d^5 but the exceptions are

A

Mn and Tc

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9
Q

A very important factor that determines the standard electrode potential is

A

Enthalpy of atomization

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10
Q

High enthalpy of atomization means

A

High boiling point

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11
Q

Metals with high enthalpy of atomization tends to be

A

Noble in their reaction

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12
Q

Which series of d block have more enthalpy of atomization

A

2d and 3d ( graph in ncert)

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13
Q

The factors affecting ionization enthalpy is

A

Attraction btw nucleus and electron
Repulsion btw Electrons
Exchange energy

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14
Q

In p block which oxidation state is favoured by heavier members

A

Lower oxidation state ( inert pair effect)

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15
Q

In d blocks which oxidation state is found to be stable for heavier members

A

High oxidation state

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16
Q

Copper is inable to liberate H2 from acids because of

A

Positive electrode potential

17
Q

Which acids react with Cu

A

Nitric acid and hot concentrated sulphuric acid

18
Q

For which all elements electrode potential is more negative than expected

A

Mn, Ni and Zn

19
Q

Beyond Mn which all have trihalides

A

Fe and Co

20
Q

Why is Cu(2+) more stable than Cu(1+) in aqueous solution ?

A

Because of more negative hydration enthalpy

21
Q

The metals of first series are reactive the exception to this is

A

Cu

21
Q

Ti(2+) , V(2+) and Cr(2+) are

A

Strong reducing agents

21
Q

Mn(3+) , Co(3+) are

A

Strong oxidizing agents

22
Q

The catalyst btw iodine and persulphate ions

A

Fe (3+)

23
Q

The melting point of interstitial compound is

A

Higher than pure metals

24
Q

As oxidation number of metal increase the

A

Ionic charecter decreases

25
Q

Mn2O7 is a

A

Covalent green oil

26
Q

CrO is

A

Basic

27
Q

Cr2O3 is

A

Amphoteric

28
Q

The Cr-O-Cr bond in dichromate is

A

126°

29
Q

The terminal Cr -O bond is

A

163pm

30
Q

The colour of pottasium permanganate is

A

Dark purple

31
Q

Pottasoum permanganate is isostructural with

A

KClO4

32
Q

Fe(3+)

A

Yellow

32
Q

Fe (2+) is

A

Green

33
Q

Strong oxidizing agent of lanthanoids is

A

Ce(4+) , Tb (4+)

34
Q

Strong reducing agent of lanthanoids are

A

Sm(2+) , Eu(2+)

35
Q

F electrons are not present in which actinoids

A

Thorium

36
Q

Which I sused in pigmentation industry

A

TiO