Alcohols Flashcards

1
Q

What is catechol

A

1,2 Dihydroxy benzene

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2
Q

Resoircinol

A

1, 3 Dihydroxy benzene

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3
Q

What is quinol ?

A

1,4 dihydroxy benzene

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4
Q

C-O bond length in alcohols is

A

142 pm

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5
Q

O-H bond length in alcohols is

A

96 pm

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6
Q

The bond angle of C-O-H in alcohols is

A

108.9°

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7
Q

The C-O bond length in Phenols is

A

136 pm

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7
Q

The bond length of C-O bond in ester is

A

141 pm

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7
Q

The bond angle of C-O-H in Phenols is

A

109°

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7
Q

Formaldehyde on rn with dry ether and grignard reagent gives

A

1° alcohol

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7
Q

The angle btw C-O-C bond in ester is

A

111.7 °

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7
Q

Ketones on rn with grignard reagent and dry ether yields

A

3° alcohol

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7
Q

Other aldehydes on rn with grignard reagent and dry ether yield

A

2°alcohol

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7
Q

Alcohol act as nucleophile while the breaking of

A

O-H bond

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7
Q

Acidity can be increased by

A

Electron withdrawing grp at ortho and para positions

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7
Q

Alcohols act as electrophile while the cleavage of

A

C-O bond

7
Q

A: water is acidic than all alcohols
R: methoI more acidic than water

A

A is false while R is true

7
Q

In reaction of alcohol with acid chloride which reagent is used

A

Pyridine

8
Q

Order of dehydration is

A

3°>2°>1°

9
Q

Cu / 573 K is a

A

Oxidation reagent

10
Q

Alcohol dehydration at 443K results in

A

Alkene

11
Q

Alcohol dehydration in 413K results in

A

Ether

12
Q

The enzyme that cnverts glucose to ethyl alcohol

A

Zymase

13
Q

Phenol cannot be distinguished from alcohol by

A

Na

14
Q

Reagent not cleaved by HI even at high temp

A

Ph-O-Ph

15
Q

Primary alcohol on Catalytic hydrogenation yields

A

Aldehyde + hydrogen gas ( rn with Cu/ 500K)

16
Q
A