chemistry of life 1,2,3 Flashcards
atoms are
units of matter
nucleus of atoms consists of
neutrons and protons
what orbits the nucleus of atoms
neg charged electrons
in a neutral atom
electrons= number of protons
energy is
the ability to do work
potential energy
the energy matter stores due to its position or location
greater the distance electrons have from the nucleus the greater their
potential energy
shell diagram
2 electrons in first shell then 8 then 8
outermost shell electrons are valence electrons
atomic number is number of electrons
atom with complete valence shell is
unreactive or inert
cation
atom that loses valence electrons and become pos charged
anion
atom that gains electrons to complete valence shell and becomes neg charged
covalent bonds
2 atoms share a pair of valence electrons
ionic bonds
transfer of electrons between pos charge and neg charge form ionic bond
compounds which form ionic bonds are
salts
hydrogen bonds
weak bond
H atom attached to an EN atom by a polar covalent bond is shared with another EN atom through weak electrical attraction
water’s cohesive forces are due to it’s
H bonds with other water molecules
any molecule or atom that has polarity will
attract water molecules and thus will dissolve in water (soluble)
van der waal’s interactions
similar to H bonds but are formed from non polar molecules where “hot spots” of pos and neg may transiently occur
hydrophobic interactions
non polar molecules do not mix readily w polar water molecules
ex fats and oils
cohesion of water that results in surface tension is due to
large proportion of water molecules being H bonded to their neighbours at any time
molecules in centre of drop of liquid are equally attracted to surrounding molecules and molecules at surface are drawn into centre way from air (they would rather interact with each other than with air) which creates surface tension
water has a high specific heat which means
amount of heat which must be absorbed / lost for 1 gram of a substance to raise/ lower its temp by 1 degree C and for water this is 1 calorie
why does temp of water NOT change as much as many other substances
because with water much of energy is used to break H bonds
solvent, solute
solvent ie the water
solute ie the substance that dissolves
form a solution
structural isomers
same formula but different structure
cis-trans isomers
differ in arrangement around a double bond
enantiomers
mirror images of each other
4 main classes of macromolecules
carbs
proteins
nucleic acids
lipids
cabrohydrates
- composed of C, H and O
- classified into:
- fibre
- starch
- complex sugars (polysaccharides)
- simple sugars (monosaccharides)
- most are ring structures
carbs for energy storage
- plant cells use polysaccharides for both storage (starch) and cell structure (cellulose)
- herbivore break down these plant polysaccharides for energy
- animal cells use polysaccharides for storage (glycogen) which can be catabolized through glycogenolysis to yield energy
proteins perform all essential functions for cells to stay alive including
- catalysis
- signalling
- structure
- energy/ gradient generation
essential vs non essential amino acids
essential need to be in diet, body cannot synthesize by itself
polypeptide chain
2 amino acids positioned so COOH group of one lines with amino group of other
dehydration rxn; peptide bond is formed between carbon and nitrogen
amino acid properties are from their various
side chains (R groups)
protein shape
- final shape important
- function of protein
- exposes binding sites
nucleic acids are
info carrying molecules
DNA –> RNA via transcription –> protein via translation
nucleic acids made up of
- high energy triphosphate
- sugar; either deoxyribose or ribose
- base; adenine, guanine, cytosine, thymine or uracil
A and T
C and G
pair through H bonds
A and T 2
C and G 3
are lipids soluble
no
lipid functions
crucial part of cell membranes
cell signalling
key energy storage reserve
most important lipids
fats, phospholipids, steroids
fats vs oil
solid vs liquid lipids
triglyceride consist of
glycerol backbone and 3 FA molecules
saturated vs unsaturated fats
saturated with H bonds ie no double bonds
essential fatty acids
- not synthesized by body
- necessary to prevent pathological conditions
- important in growth phase of children
- may protect against cardiovascular disease in adults
phospholipids make up all animal
cell membranes
how do phospholipids differ from fats
only 2 FAs bound to glycerol backbone, third carbon bound to a phosphate group
hydrophilic head; water soluble
hydrophobic tails
naturally form bilayers in water
cholesterol made where
liver
is cholesterol absorbed well in diet
no
where is cholesterol often found
in many animal cell membranes; influences membrane fluidity
what is the precursor molecule of all steroids
cholesterol
anabolism
energy is stored in cells or used to help build up and repair structures of body
catabolism
breakdown of body tissues into simples forms, which can then be used to create energy
by product of metabolism is
heat
endergonic rxns
absorb free energy (anabolic)