Ch. 4 Estimating Potential Harm & Planning A Response Flashcards
Two main organizations establish/publish toxicological data used by hazmat/WMD responders:
ACGIH
OSHA
The point at which a hazardous material/WMD begins to affect a person.
TLV Threshold Limit Value
Damage a hazmat/WMD will inflict on a human being is a function of the _______________ of the released substance, as well as the ___________ along with the ___________.
Physical and chemical PROPERTIES.
CONDITIONS under which it was released.
DURATION of the exposure.
pain CPD will inflict on a human being
Systems established by ACGIH, OSHA and NIOSH
ACGIH = TLV OSHA = PEL (the Established standard limit of exposure-hazmat) NIOSH = REL (recommended exposure limit)
ACGIH = guidelines OSHA = law
PEL, REL, and TLV/TWA measure maximum, time weighted concentration of material to which ____________ can be exposed to w/o suffering any adverse effects over ______________.
95% of healthy adults.
40 hr workweek
The _______ is the established standard limit of exposure to a hazardous material.
Permissible exposure limit (PEL)
PEL-OSHA, which is law. ACGIH is guidelines
Gases expressed:
ppm, ppb, ppt
Substances other than gases.
Fibers and dusts
mg/m3
Max concentration person exposed to 15 min, 4 times a day with no chronic/irreversible tissue damage. Minimum 1 hr rest period.
TLV/STEL
Max airborne concentration exposed 8 hrs a day, 40 hrs a week with NO ILL effects
TLV/TWA
Max concentration worker should not be exposed to, for even a second
TLV/C
Direct or airborne contact with material could result in possible or significant exposure from absorption through skin, mucous membranes or eyes.
Threshold limit value/skin
REL
Recommended exposure limit, established by NIOSH and similar to PEL
Three types of IDLH atmospheres:
Toxic.
Flammable.
Oxygen deficient.
Exposure guidelines used to identify 3 basic atmospheres or environments at hazmat/WMD emergency?
Green-low hazard/risk. Normal work uniform.
Yellow-hazard increasing. Some level of PPE (splash/some level respiratory).
Red-high hazard/risk. Highest level of skin/respiratory. Unprotected fatal. Above IDLH.
Levels of atmospheres (3)
Safe-no harmful hazmat, can handle routine emergencies w/o PPE.
Unsafe-hazmat no longer contained, has created unsafe condition/atmosphere. Exposed will probably experience some form of acute/chronic injury.
Dangerous-serious, irreversible injury or death may occur
Atmospheric concentration of a toxic, corrosive or asphyxiant substance poses an immediate threat to life or could cause irreversible or delayed adverse health effects.
IDLH
(Hazmat) Number of exposures determined by: (3)
Location of incident.
Physical/chemical properties.
Amount of progress in protecting exposures by isolating released site or taking protective actions (evac or shelter in place).
_____________ is one of the first actions responders must take at a hazardous materials/WMD incident.
Isolation of the hazard area
Isolating a contaminated atmosphere is always conjoined in some way with:
Denial of entry (I.e. restriction of access) to the site
Sheltering in place. The method is desirable only when the population being protected in place:
Can care for themselves.
Control the air.
Structure can be sealed.
P. 88 A small spill means that a spill involves: (ERG)
Less than 52 gallons (200L) of liquid.
Less than 661 pounds (300kg) of solid
A ________ of any kind contains a large amount of solute for a given amount of solution.
A _________, by contrast, contains a small amount of solute for a given solution.
Concentrated solution.
Dilute solution
NFPA 472 awareness are “______” where OSHA awareness are “_________”.
Personnel.
Responders
______ level personnel could be expected to initiate some form of protective action such as
- directing civilians away from contaminated area OR
- directing certain populations of civilians to shelter in place
Awareness
To estimate size of release, subtract _____________ from __________.
Amount remaining IN the container.
Maximum capacity of container.
-computed by looking at shipping paper to see whether deliveries have been made
estimations “quite rough”
_________ , when discussing corrosives, is an expression of how much of the acid or the base is dissolved in a solution, usually water.
Concentration
Flammable range of natural gas
5-15%
4-14% in H.O.T.
Using detection and monitoring equipment properly requires: (3)
Some technical EXPERTISE.
A LOT of common sense.
Commitment to CONTINUAL training.
The strength of a corrosive refers to the degree of ________ that occurs in a solution.
Ionization
The words “strong” and “weak” do NOT correspond with :
“concentrated” and “dilute”
Strong corrosive will react more _____ with ______ materials such as _________
AND be more _______ when they come in to contact with _____ such as ________.
Vigorously, incompatible, organic substances
Aggressive, metallic, metal shelving/shovels
aggressive rock=Metallica
Skin absorption is enhanced by (4)
Abrasions.
Cuts.
Heat.
Moisture.
Acids have a strong affinity for ______ while alkaline material dissolves _________ that make up skin tissue and change solid tissue into a soapy-like liquid.
Moisture.
Fats and lipids
______ burns are often much deeper and more destructive than are _____ burns.
Alkaline.
Acid