cgier 33 Flashcards
– is a reaction that takes place in either directions and the forward and reverse proceed at the — and they reach —
- reversible reactions
- same rate
- equilibrium
dynamic equilibrium is the equilibrium between two phases is —
physical equilibrium
h20 (l) –> h20 (g)
when the rate of the forward and the reverse are equal and the concentration no longer change this is known as —-
chemical equilibrium
relates the concentration of the reactants and the products at equilibrium in term of QUANTITY is — and is the ratio of —– raised to the power of their —-
-equilibrium constant (k)
(keq = products / reactants)
- equilibrium concentration
- stiocmetric coefficient
the value of k is — regardless its —- and its depended on — and — and has no —
- constant , initial concnetration
- temp and the reaction
- unitless
Kc refers to equilibrium concentration in —-
Kp refers to equilibrium concentration of —-
-moles/l aka molarity
- pressure
-solids are excluded from the ratio bc they are fixed by its – and doesn’t —
- pure liquids are excluded from the ratio bc they are — and doesn’t —
- density , doesn’t change
- very high , doesn’t change
the equilibrium constant can be expressed as — in gasses
partial pressures
the k of the reverse reaction is the – of the forward reaction
- reciprocal
- k fwd = 1/ l rev
is k»_space; 1 , its — favoured because products are — than reactants at 25 celsius
- product favoured
- more than
k «1 , its – favoured because the reactants are —
- reactant favoured
- reactants are more than products
- as 1.8 x 10 power 5
if any external stress is applied to a system at equilibrium , the system adjust in such a way that the stress is partially offset to re-establish the equiliburm is —- principle and stresses can be:
- Le chattier principle
- change in concentration of products or reactants
- change in temp
- change in pressure or volume
- catalyst
increasing the concentration of the reactants will move the equilibrium to the
right , products
increase in temp in exothermic will move the equilibrium to the — and decreasing moves it —
increase in temp in endothermic moves it to the — and decreasing the temp moves it —
- reactant , product
- product , reactant
increasing the pressure will shift the equilburm to the side with – number of moles
increasing the volume will shift the equiburm to side with –
if number of moles on reactant and products = then —
- few because the volume decreased
- more moles
- no effect on equilibrium