cgier 33 Flashcards

1
Q

– is a reaction that takes place in either directions and the forward and reverse proceed at the — and they reach —

A
  • reversible reactions
  • same rate
  • equilibrium
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1
Q

dynamic equilibrium is the equilibrium between two phases is —

A

physical equilibrium
h20 (l) –> h20 (g)

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2
Q

when the rate of the forward and the reverse are equal and the concentration no longer change this is known as —-

A

chemical equilibrium

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3
Q

relates the concentration of the reactants and the products at equilibrium in term of QUANTITY is — and is the ratio of —– raised to the power of their —-

A

-equilibrium constant (k)
(keq = products / reactants)
- equilibrium concentration
- stiocmetric coefficient

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4
Q

the value of k is — regardless its —- and its depended on — and — and has no —

A
  • constant , initial concnetration
  • temp and the reaction
  • unitless
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5
Q

Kc refers to equilibrium concentration in —-
Kp refers to equilibrium concentration of —-

A

-moles/l aka molarity
- pressure

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6
Q

-solids are excluded from the ratio bc they are fixed by its – and doesn’t —
- pure liquids are excluded from the ratio bc they are — and doesn’t —

A
  • density , doesn’t change
  • very high , doesn’t change
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7
Q

the equilibrium constant can be expressed as — in gasses

A

partial pressures

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8
Q

the k of the reverse reaction is the – of the forward reaction

A
  • reciprocal
  • k fwd = 1/ l rev
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9
Q

is k&raquo_space; 1 , its — favoured because products are — than reactants at 25 celsius

A
  • product favoured
  • more than
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10
Q

k «1 , its – favoured because the reactants are —

A
  • reactant favoured
  • reactants are more than products
  • as 1.8 x 10 power 5
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11
Q

if any external stress is applied to a system at equilibrium , the system adjust in such a way that the stress is partially offset to re-establish the equiliburm is —- principle and stresses can be:

A
  • Le chattier principle
  • change in concentration of products or reactants
  • change in temp
  • change in pressure or volume
  • catalyst
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12
Q

increasing the concentration of the reactants will move the equilibrium to the

A

right , products

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13
Q

increase in temp in exothermic will move the equilibrium to the — and decreasing moves it —
increase in temp in endothermic moves it to the — and decreasing the temp moves it —

A
  • reactant , product
  • product , reactant
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14
Q

increasing the pressure will shift the equilburm to the side with – number of moles
increasing the volume will shift the equiburm to side with –
if number of moles on reactant and products = then —

A
  • few because the volume decreased
  • more moles
  • no effect on equilibrium
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15
Q

during excerise there will be build up of lactic acid ( h+) because –

A
  • more co2 and h+ will be exhaled
  • so equilibrium moves to the left
  • formala: c02 + h20 –> h2c03 –> h+ + hco3-
  • aka hyperventilating , breathe into a paper bag to shift the equilibrium to the right if co2 is building up
16
Q

at sea level 02 pressure is —
at high altitudes 02 has a pressure of —

A
  • 0.2 1atm
  • 0.14 atm
  • in lungs: hb + 402 –> hb (02)4
  • shifts to the left Ieft in case of hypoxia aka deffincy in 02 which causes headaches , nausea and fatigue