Carbohydrates Flashcards
Carbohydrates
Carbohydrates are among the “macronutrients” that provide substantial metabolic energy.
Phytate
Phosphate-containing saccharide found primarily in cereal brans (1% in oat and 3.7% in wheat brans). They substantially bind cations (ex. Zn2+)
Give three examples of disaccharides
- Lactose 2. Sucrose 3. Lactulose
Examples of polysaccharides
- Starches: amylose, amylopectin, glycogen 2. Hemicellulose, cellulose, pectins, and gums
Lactose
ß- 1,4 linked galactose + glucose
Lactose is unique to what?
- Milk, the primary carbohydrate in milk
- A significant portion of the energy in milk
- Contributes substantially to osmolarity of milk
- A poor substrate for pathogenic microbes
What is unique about birds regarding lactose?
Birds do not digest lactose; they will develop diarrhea when given liquid milk or milk powder containing lactose.
Is lactose readily digestable in adults?
- No, lactose is not readily digested in adults
- The beta-1,4 linkage in lactose is resistance to hydrolysis by disaccharidases present in adults. Saccharides digested in animals have alpha-1,4 linkages
- Lactose is cleaved in young animals by transient expression of “lactase”, a disaccharidase specific for lactose
Lactulose
- beta-1,4 linked galactose + fructose
- Not hydrolyzed by mammalian enzymes
- Hydrolyzed by some gastrointestinal microbial enzymes
Sucrose
- alpha 1,4-linked glucose + fructose
- Digested by animals, even cats
Sucrose - Dogs
- A positive effect on the acceptability of food
- A “humectant” in the manufacture of semi-moist foods (humectant –> keeps food moist)
Sucrose - Cats
- Indifferent to sucrose and other sweet substances
- Causes fructosuria in high dietary concentrations, >15% of diet
Starch
- alpha 1,4 and 1,6 linkages of glucose
- Straight chains (amylose) or in chains with branches (amylopectin in plants, and glycogen in animals)
- Plant starches occur in….
- Plant starches occur in semicrystalline granules
- Granules are variably resistant to digestion
What does high moisture and heat do to the semicrystalline granules of plant starches?
- High moisture and heat (as with cooking of starches in commercial canned and dry expanded diets) “gelatinize” granules
- Melts and hydrates starch crystals
- Transforms starch structurally
- Increases digestibility of starches