carbohydrates Flashcards
what are carbohydrates used for?
energy, storage of energy, + cell adhesion molecules
carbon-hydrogen-oxygen ratio in carbs
1 carbon : 2 hydrogen : 1 oxygen
monosaccharides
single sugar. subdivided by number of carbons
disaccharides
two sugars
disaccharide examples
maltose, sucrose, lactose
oligosaccharides
3-10 sugars
polysaccharides
more than 10 sugars
polysaccharide examples
starch + dextrin
3 carbon monosaccharide name
triose
4 carbon monosaccharide name
tetrose
5 carbon monosaccharide name
pentose
6 carbon monosaccharide name
hexose
9 carbon monosaccharide name
nonose
monosaccharide functional groups
aldehyde + ketone
glucose functional group
aldehyde aka aldose
fructose functional group
ketone aka ketose
stereoisomers
presence of chiral carbons
what is a chiral carbon?
a carbon w/4 different atoms/groups bonded to it
D-isomers
naturally occurring in carbs
hemiacetal
aldehyde reacts w/alcohol group to form acetal bond
hemiketal
ketone reacts w/alcohol group to form a hemiketal bond
pyranose (ring structure)
6 member ring
furanose (ring structure)
5 member ring
anomers
ring structure can open + re-close allowing rotation at carbon #1
what is another name for the rotation that occurs in anomers?
mutorotation
alpha anomers
OH (alcohol) group drawn down on carbon #1
what type of anomers does dextrose have?
mix of alpha and beta anomers. aka d-glucose
beta anomers
OH (alcohol) group drawn up on carbon #1
epimers
stereoisomers that differ in the position of a hydroxyl group at only one asymmetric carbon atom
what type of glucose epimer molecule is altered at carbon #4?
galactose
what type of glucose epimer molecule is altered at carbon #2?
mannose
sucrose composition
glucose + fructose
sucrose common food name
table sugar
lactose composition
galactose + glucose
lactose common food name
milk sugar
maltose composition
glucose + glucose
maltose common food name
malt sugar
what is the name of the polymer of glucose?
glucosan
starch common food source
cereals, potatoes, veggies
amylose structure
non-branching (linear)
amylopectin structure
found in plants. non-branching (linear) + branching isomers
glycogen structure
non-branching (linear) + branching isomers. branching more common
location of glycogen
liver + muscle
function of glycogen
storage form of glucose
cellulose structure
non-branching (linear), can’t break down
insoluble fibers
decreases bowel transit time, gives stool “bulk”
soluble fibers
protects against cardiovascular disease. gives feeling of “fullness” after eating
inulin
polymer of fructose (fructosan)
proteoglycans
GAG linked to core protein. “bottle-brush” appearance
what is another name for proteoglycans?
mucosaccharides